Surfactant adsorption dynamics

被引：20
作者：
Eastoe, J
Rankin, A
Wat, R
Bain, CD
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
来源：
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY | 2001年 / 20卷 / 03期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1080/01442350121251
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Advances in techniques for investigating dynamic adsorption of surfactants at the air-water interface are discussed. Of particular interest are the maximum-bubble-pressure method. and the interrogation of adsorption layers on an overflowing cylinder (OFC) cell using ellipsometry, surface-light scattering, laser Doppler velocimetry and neutron reflection. Recent studies described here, with a model di-chain anionic fluorocarbon surfactant sodium bis(1H, 1H-nonafluoro-n-pentyl) sulphosuccinate (di-CF4) demonstrate that the OFC presents an ideal flexible platform for investigating dynamics of adsorption from solutions. Under certain conditions the behaviour is consistent with an activated-diffusion mechanism, as has been found previously fur simple alcohols and various other non-ionic and ionic surfactants.
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收藏
页码：357 / 386
页数：30
相关论文
共 94 条
[1]   Apparent anomalies in surface excesses determined from neutron reflection and the Gibbs equation in anionic surfactants with particular reference to perfluorooctanoates at the air/water interface [J].
An, SW ;
Lu, JR ;
Thomas, RK ;
Penfold, J .
LANGMUIR, 1996, 12 (10) :2446-2453
[2]   KINETICS OF STEP-WISE MICELLE ASSOCIATION [J].
ANIANSSON, EA ;
WALL, SN .
JOURNAL OF PHYSICAL CHEMISTRY, 1974, 78 (10) :1024-1030
[3]   THEORY OF KINETICS OF MICELLAR EQUILIBRIA AND QUANTITATIVE INTERPRETATION OF CHEMICAL RELAXATION STUDIES OF MICELLAR SOLUTIONS OF IONIC SURFACTANTS [J].
ANIANSSON, EAG ;
WALL, SN ;
ALMGREN, M ;
HOFFMANN, H ;
KIELMANN, I ;
ULBRICHT, W ;
ZANA, R ;
LANG, J ;
TONDRE, C .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (09) :905-922
[4]   CORRECTION AND IMPROVEMENT OF ON KINETICS OF STEP-WISE MICELLE ASSOCIATION BY ANIANSSON,EAG AND WALL,SN [J].
ANIANSSON, EAG ;
WALL, SN .
JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (08) :857-858
[5]   On the factor in Gibbs equation for ionic surfactants [J].
Bae, S ;
Haage, K ;
Wantke, K ;
Motschmann, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (07) :1045-1050
[6]   Rates of mass transfer and adsorption of hexadecyltrimethylammonium bromide at an expanding air-water interface [J].
Bain, CD ;
Manning-Benson, S ;
Darton, RC .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 229 (01) :247-256
[7]   KINETICS OF ADSORPTION FROM A SOLUTION . ROLE OF DIFFUSION AND OF ADSORPTION-DESORPTION ANTAGONISM [J].
BARET, JF .
JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (08) :2755-&
[8]   SURFACE DILATION AND FLUID-DYNAMICAL BEHAVIOR OF NEWTONIAN LIQUIDS IN AN OVERFLOWING CYLINDER .2. SURFACTANT SOLUTIONS [J].
BERGINKMARTENS, DJM ;
BOS, HJ ;
PRINS, A .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1994, 165 (01) :221-228
[9]   SURFACE DILATION AND FLUID-DYNAMIC BEHAVIOR OF NEWTONIAN LIQUIDS IN AN OVERFLOWING CYLINDER .1. PURE LIQUIDS [J].
BERGINKMARTENS, DJM ;
BOS, HJ ;
PRINS, A ;
SCHULTE, BC .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1990, 138 (01) :1-9
[10]   ADSORPTION DYNAMICS OF SURFACTANTS AT THE AIR/WATER INTERFACE - A CRITICAL-REVIEW OF MATHEMATICAL-MODELS, DATA, AND MECHANISMS [J].
CHANG, CH ;
FRANSES, EI .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 100 :1-45
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