Synthesis and Magnetic Properties of [Ni3(BTC)2(H2O)12]n (BTC=1,3,5-Benzenetricarboxylate)

被引:0
|
作者
Bi, Jian-Hong [1 ]
Li, Meng [2 ]
Yao, Zi-Lu [3 ]
机构
[1] Hefei Normal Univ, Dept Chem & Chem Engn, Hefei, Peoples R China
[2] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
[3] Henan Polytechn Univ, Dept Chem Engn & Technol, Sch Mat Sci & Engn, Jiaozuo 454003, Peoples R China
关键词
Nickel(II) complex; Coordination polymer; Self-assemble; Magnetic property;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A self-assembled coordination polymer with the composition, [Ni-3(BTC)(2)(H2O)(12)](n) (BTC = 1,3,5-benzenetricarboxylate radical) has been synthesized and characterized by IR spectra and elemental analysis. The magnetic properties shows that there are weak antiferromagnetic interactions between the Ni(II) ions of in molecule of the coordination polymer.
引用
收藏
页码:5181 / 5182
页数:2
相关论文
共 50 条
  • [1] Synthesis and characterization of strontium 1,3,5-benzenetricarboxylate, [Sr3(1,3,5-BTC)2(H2O)4]•H2O
    Tran, Dat T.
    Chu, Deryn
    Oliver, Allen G.
    Oliver, Scott R. J.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (05) : 351 - 354
  • [2] Synthesis and crystal structure of a Nickel(II) complex [Ni(H2btc)2(hmta)2(H2O)] with 1,3,5-benzenetricarboxylate and hexamethylenetetramine
    Lin, H
    Feng, YL
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (05) : 573 - 575
  • [3] Study of the mechanochemical formation and resulting properties of an archetypal MOF: Cu3(BTC)2 (BTC=1,3,5-benzenetricarboxylate)
    Yuan, Wenbing
    Garay, Ana Lazuen
    Pichon, Anne
    Clowes, Rob
    Wood, Colin D.
    Cooper, Andrew I.
    James, Stuart L.
    CRYSTENGCOMM, 2010, 12 (12): : 4063 - 4065
  • [4] Simple Preparation, Structure and Conductivity of Nickel(Ⅱ) Benzenetricarboxylate Ni3(BTC)2·12H2O
    谭海燕
    刘城
    王朝晖
    吴金平
    Chinese Journal of Structural Chemistry, 2014, (03) : 401 - 406
  • [5] Structure and magnetic properties of a novel two-dimensional complex from 1,3,5-benzenetricarboxylate and neodymium(III) -: {[Nd(1,3,5-benzenetricarboxylate)(H2O)4]•H2O}n
    Wang, QL
    Liang, M
    Liao, DZ
    Yan, SP
    Jiang, ZH
    Cheng, P
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (04): : 613 - 616
  • [6] Simple Preparation, Structure and Conductivity of Nickel(II) Benzenetricarboxylate Ni3(BTC)2•12H2O
    Tan Hai-Yan
    Liu Cheng
    Wang Zhao-Hui
    Wu Jin-Ping
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (03) : 401 - 406
  • [7] Syntheses and crystal structures of three novel coordination polymers:: [M2(bpy)(btc)(OH)]n (M = Ni,Co) and {[Co1.5(bpy)(btc)]•(H2O)2}n (bpy=2,2′-bipyridine, btc=1,3,5-benzenetricarboxylate)
    Wang, YQ
    Cao, R
    Sun, DF
    Bi, WH
    Li, X
    Li, XJ
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 657 (1-3) : 301 - 309
  • [8] Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(H2btc)2(hmta)2(H2O)] with 1,3,5- Benzenetricarboxylate and Hexamethylenetetramine
    林鸿
    冯云龙
    Chinese Journal of Structural Chemistry, 2005, (05) : 573 - 575
  • [9] 3-D indium(III)-btc channel frameworks and their ion-exchange properties (btc=1,3,5-benzenetricarboxylate)
    Lin, ZZ
    Chen, L
    Yue, CY
    Yuan, DQ
    Jiang, FL
    Hong, MC
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (04) : 1154 - 1160
  • [10] Low temperature heat capacity study of Co3(BTC)2•12H2O and Ni3(BTC)2•12H2O
    Li, Rongchun
    Luo, Jipeng
    Yan, Huimin
    Zheng, Hui
    Wei, Rongmin
    Yang, Min
    Gu, Xiangling
    Tan, Zhicheng
    Shi, Quan
    THERMOCHIMICA ACTA, 2021, 699