Synthesis and Reactivity of Heterobimetallic Co-PAlP Pincer Complexes

被引：3

作者：

Semba, Kazuhiko ^{[1
]}

Shimoura, Fumiya ^{[1
]}

Nakao, Yoshiaki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2022年 / 51卷 / 04期

关键词：

Heterobimetallic complex; Cobalt; Aluminium; D-BLOCK ELEMENTS; METAL-COMPLEXES; COBALT; BORYL; DEHYDROGENATION; HYDROGENATION; ACTIVATION; ALANES; BOND;

D O I：

10.1246/cl.220008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cobalt complex ligated with a PAlP pincer ligand was synthesized. The Lewis acidity of the aluminum atom on the cobalt complex was confirmed by coordination with 4-dimethylaminopyridine (DMAP). Reactions of the cobalt complex with H2O, EtOH, i-PrOH, and t-BuOH efficiently afforded the corresponding cobalt hydride complexes.

引用

页码：455 / 457

页数：3

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