Synthesis and Reactivity of Heterobimetallic Co-PAlP Pincer Complexes

被引：3

作者：

Semba, Kazuhiko ^{[1
]}

Shimoura, Fumiya ^{[1
]}

Nakao, Yoshiaki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2022年 / 51卷 / 04期

关键词：

Heterobimetallic complex; Cobalt; Aluminium; D-BLOCK ELEMENTS; METAL-COMPLEXES; COBALT; BORYL; DEHYDROGENATION; HYDROGENATION; ACTIVATION; ALANES; BOND;

D O I：

10.1246/cl.220008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cobalt complex ligated with a PAlP pincer ligand was synthesized. The Lewis acidity of the aluminum atom on the cobalt complex was confirmed by coordination with 4-dimethylaminopyridine (DMAP). Reactions of the cobalt complex with H2O, EtOH, i-PrOH, and t-BuOH efficiently afforded the corresponding cobalt hydride complexes.

引用

页码：455 / 457

页数：3

共 50 条

[21] Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand
Hood, Thomas M.
Chaplin, Adrian B.
DALTON TRANSACTIONS, 2021, 50 (07) : 2472 - 2482
[22] Synthesis and reactivity of monocyclopentadienyl tantalum complexes with pincer dialkoxide ligands
Fandos, R
López-Solera, I
Otero, A
Rodríguez, A
Ruiz, MJ
Terreros, P
ORGANOMETALLICS, 2004, 23 (21) : 5030 - 5036
[23] Synthesis and Reactivity of Iron Complexes with a Biomimetic SCS Pincer Ligand
Speelman, Amy L.
Skubi, Kazimer L.
Mercado, Brandon Q.
Holland, Patrick L.
INORGANIC CHEMISTRY, 2021, 60 (03) : 1965 - 1974
[24] Synthesis and reactivity of IrIII CCC-NHC pincer complexes
Schultz, Katherine M.
Kaminsky, Werner
Goldberg, Karen I.
Heinekey, Michael
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[25] Synthesis & reactivity of novel silyl/silylene pincer cobalt complexes
Zhang, Jia
Foley, Bryan
Bhuvanesh, Nattamai
Whited, Matthew
Ozerov, Oleg
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[26] Synthesis, characterization, and reactivity of electrophilic iridium and rhodium pincer complexes
Findlater, Michael
Brookhart, Maurice
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[27] Synthesis and Characterization of a Family of POCOP Pincer Complexes with Nickel: Reactivity Towards CO2 and Phenylacetylene
Jonasson, Klara J.
Wendt, Ola F.
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (37) : 11894 - 11902
[28] Facile synthesis of heterobimetallic compounds from the cyclopentadienylruthenium moiety and group 10 POCOP pincer complexes
Angel Espinosa-Jalapa, Noel
Hernandez-Ortega, Simon
Morales-Morales, David
Le Lagadec, Ronan
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 716 : 103 - 109
[29] Synthesis and Reactivity of PtII Methyl Complexes Supported by Pyrazolate Pincer Ligands
Zahora, Braden A.
Gau, Michael R.
Goldberg, Karen, I
ORGANOMETALLICS, 2020, 39 (08) : 1230 - 1237
[30] Synthesis, Structure, and Reactivity of Nitrosyl Pincer-Type Rhodium Complexes
Gaviglio, Carina
Ben-David, Yehoshoa
Shimon, Linda J. W.
Doctorovich, Fabio
Milstein, David
ORGANOMETALLICS, 2009, 28 (06) : 1917 - 1926

← 1 2 3 4 5 →