The physicochemical properties of the surface of copper nanopowders prepared by the electroexplosion and gas-phase methods

被引:0
作者
Fedushchak, T. A. [1 ]
Ermakov, A. E. [2 ]
Uimin, M. A. [2 ]
Galanov, S. I. [1 ]
Velichkina, L. M. [1 ]
Sedoi, V. S. [3 ]
Vosmerikov, A. V. [1 ]
Petrenko, T. V. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem, Siberian Branch, Tomsk 634055, Russia
[2] Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620219, Russia
[3] Russian Acad Sci, Inst High Current Elect, Siberian Branch, Tomsk 634055, Russia
关键词
D O I
10.1007/s11504-008-4017-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The temperature-programmed ammonia desorption, IR spectroscopy, differential thermal analysis, and inorganic test-reagent methods were used to study the properties of copper nanopowders prepared under various conditions of wire electroexplosion and gas-phase synthesis. Electroexplosion in nitrogen was shown to favor the formation of copper nanopowders with acid surface properties. Explosion in argon produced powders with reducing surface properties, which could be detected in aqueous solutions of ammonia and iodine during several minutes.
引用
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页码:608 / 611
页数:4
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