Epoxy resins modified with poly(vinyl acetate)

被引：11

作者：

Lapprand, A

Arribas, C ^{[1
]}

Salom, C

Prolongo, MG

机构：

[1] Univ Politecn Madrid, ETSI Aeronaut, Madrid, Spain

[2] Univ Politecn Madrid, EUIT Aeronaut, Madrid, Spain

来源：

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY | 2003年 / 143卷

关键词：

epoxy resin; DGEBA; poly(vinyl acetate); curing; differential scanning calorimetry;

D O I：

10.1016/S0924-0136(03)00356-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Miscibility and curing behaviour have been studied in blends of poly(vinyl acetate) (PVAc) with diglycidyl ether of bisphenol A (DGEBA) resin and 4,4'-diaminodiphenylsulphone (DDS) used as curing agent. The PVAc component was used as a potential toughness modifier. Binary mixtures DGEBA + PVAc show complete miscibility over the whole composition range. Ternary mixture DGEBA + DDS in stoichiometric ratio +10% (w/w) PVAc behaves also as homogeneous phase. However PVAc was found to be inmmiscible with the highly amine-cross-linked epoxy resin. It was found that phase separation in DGEBA + DDS + PVAc blends occurred as the conversion reaches a value close to 40%. In the final cured material two phases are present: an epoxy phase and a PVAc phase. It was also found a slow down of the reaction when PVAc was present. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：827 / 831

页数：5

共 50 条

[1] STRUCTURAL TRANSITIONS IN MODIFIED POLY EPOXY RESINS
GURMAN, IM
OHOLOKHO.AB
FREIDIN, AS
KIEM, VB
GRINEVSK.LA
BERNATSK.AD
AKUTIN, MS
VYSOKOMOLEKULYARNYE SOEDINENIYA SECTION B, 1970, 12 (10): : 776 - &
[2] Synthesis of Modified Poly(vinyl acetate) Adhesives
Salvini, A.
Saija, L. M.
Lugli, M.
Cipriani, G.
Giannelli, C.
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2010, 24 (8-10) : 1629 - 1651
[3] The influence of UV-irradiation on poly(vinyl chloride) modified by poly(vinyl acetate)
Kaczmarek, H
Drag, R
Swiatek, M
Oldak, D
SURFACE SCIENCE, 2002, 507 : 877 - 882
[4] Influence of novel amine adduct on curing of epoxy resins in presence of vinyl acetate
Asian Paints Ltd, Bombay, India
J Coat Technol, 842 (41-46):
[5] Preparation and Properties of Poly(vinyl acetate) Adhesive Modified with Vinyl Versatate
Ma, Guoyan
Wang, Le
Wang, Xiaorong
Wang, Chengjun
Li, Xi
Li, Lu
Ma, Hongfei
MOLECULES, 2023, 28 (18):
[6] Modification of Poly(Vinyl Chloride) Compositions with Cyclocarbonate Derivatives of Epoxy Resins
Stroganov V.F.
Abdrakhmanova L.A.
Polymer Science - Series D, 2019, 12 (01) : 20 - 23
[7] Potential substitutes for discontinued poly(vinyl acetate) resins used in conservation
Alderson, Samantha
Down, Jane L.
Maines, Christopher A.
Williams, R. Scott
Young, Gregory S.
JOURNAL OF THE AMERICAN INSTITUTE FOR CONSERVATION, 2019, 58 (03) : 158 - 179
[8] Performance of Membrane with Poly(vinyl acetate) Modified by Starch
Zhang, Yan Hua
Gu, Jiyou
Shi, Junyou
Di, Mingwei
Li, Zhiguo
Tan, Haiyan
Qiu, Si
ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (17) : 9985 - 9988
[9] Poly(ethylene-co-vinyl acetate)-graft-poly(methyl methacrylate) (EVA-graft-PMMA) as a modifier of epoxy resins
García, FG
Soares, BG
Williams, RJJ
POLYMER INTERNATIONAL, 2002, 51 (12) : 1340 - 1347
[10] ANALYSIS OF ALKYD RESINS MODIFIED WITH VINYL CHLORIDE-ACETATE COPOLYMER
SWANN, MH
ESPOSITO, GG
ANALYTICAL CHEMISTRY, 1954, 26 (06) : 1054 - 1055

← 1 2 3 4 5 →