Tip-enhanced Raman scattering of p-thiocresol molecules on individual gold nanoparticles

被引：34

作者：

Chen, Jianing ^{[1
,2
]}

Yang, Weisheng ^{[1
]}

Dick, Kimberly ^{[3
]}

Deppert, Knut ^{[3
]}

Xu, H. Q. ^{[3
]}

Samuelson, Lars ^{[3
]}

Xu, Hongxing ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100080, Peoples R China

[2] Dalian Univ Technol, Sch Phys & Optoelect, Dalian 116024, Peoples R China

[3] Lund Univ, Div Solid State Phys, SE-22100 Lund, Sweden

来源：

APPLIED PHYSICS LETTERS | 2008年 / 92卷 / 09期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1063/1.2837543

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We present a study of tip-enhanced Raman scattering on Au aerosol nanoparticles deposited on gold films. Under the tunneling current state, the Au tip and the Au aerosol nanoparticle form a narrow cavity, where large electromagnetic field enhancements are created to enhance Raman scattering enormously. Colorless p-thiocresol molecules are used as probe molecules. The estimated Raman enhancement is about nine orders of magnitude for the tip/particle configuration. (c) 2008 American Institute of Physics.

引用

页数：3

共 28 条

[1] Locally enhanced Raman spectroscopy with an atomic force microscope [J].

Anderson, MS .

APPLIED PHYSICS LETTERS, 2000, 76 (21) :3130-3132

[2] Toward Raman fingerprints of single dye molecules at atomically smooth Au(111) [J].

Domke, Katrin F. ;

Zhang, Dai ;

Pettinger, Bruno .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) :14721-14727

[3] Self-assembled monolayers of aromatic thiols stabilized by parallel-displaced π-π stacking interactions [J].

Dou, RF ;

Ma, XC ;

Xi, L ;

Yip, HL ;

Wong, KY ;

Lau, WM ;

Jia, JF ;

Xue, QK ;

Yang, WS ;

Ma, H ;

Jen, AKY .

LANGMUIR, 2006, 22 (07) :3049-3056

[4]

*GAUSS INC, 2003, GAUSSIAN 03 REV B 05, P53508

[5] High-resolution near-field Raman microscopy of single-walled carbon nanotubes -: art. no. 095503 [J].

Hartschuh, A ;

Sánchez, EJ ;

Xie, XS ;

Novotny, L .

PHYSICAL REVIEW LETTERS, 2003, 90 (09) :4

[6] Detection of an individual single-wall carbon nanotube by tip-enhanced near-field Raman spectroscopy [J].

Hayazawa, N ;

Yano, T ;

Watanabe, H ;

Inouye, Y ;

Kawata, S .

CHEMICAL PHYSICS LETTERS, 2003, 376 (1-2) :174-180

[7] Near-field Raman scattering enhanced by a metallized tip [J].

Hayazawa, N ;

Inouye, Y ;

Sekkat, Z ;

Kawata, S .

CHEMICAL PHYSICS LETTERS, 2001, 335 (5-6) :369-374

[8] SURFACE RAMAN SPECTROELECTROCHEMISTRY .1. HETEROCYCLIC, AROMATIC, AND ALIPHATIC-AMINES ADSORBED ON ANODIZED SILVER ELECTRODE [J].

JEANMAIRE, DL ;

VANDUYNE, RP .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 84 (01) :1-20

[9] Ultrasensitive chemical analysis by Raman spectroscopy [J].

Kneipp, K ;

Kneipp, H ;

Itzkan, I ;

Dasari, RR ;

Feld, MS .

CHEMICAL REVIEWS, 1999, 99 (10) :2957-+

[10] Design of near-field optical probes with optimal field enhancement by finite difference time domain electromagnetic simulation [J].

Krug, JT ;

Sánchez, EJ ;

Xie, XS .

JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (24) :10895-10901

← 1 2 3 →