Band gaps of wurtzite ScxGa1-xN alloys

被引:20
作者
Tsui, H. C. L. [1 ]
Goff, L. E. [1 ,2 ]
Rhode, S. K. [3 ]
Pereira, S. [4 ,5 ]
Beere, H. E. [2 ]
Farrer, I. [2 ]
Nicoll, C. A. [2 ]
Ritchie, D. A. [2 ]
Moram, M. A. [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England
[2] Univ Cambridge, Dept Phys, Cambridge CB3 0HE, England
[3] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England
[4] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal
[5] Univ Aveiro, Dept Phys, P-3810193 Aveiro, Portugal
基金
英国工程与自然科学研究理事会;
关键词
LIGHT-EMITTING-DIODES; ELECTRONIC-PROPERTIES; CUBIC GAN; SCGAN; FILMS; SCN; MICROSTRUCTURE; SPECTRA; SCAS;
D O I
10.1063/1.4916679
中图分类号
O59 [应用物理学];
学科分类号
摘要
Optical transmittance measurements on epitaxial, phase-pure, wurtzite-structure ScxGa1-xN films with 0 <= x <= 0.26 showed that their direct optical band gaps increased from 3.33 eV to 3.89 eV with increasing x, in agreement with theory. These films contained I-1- and I-2-type stacking faults. However, the direct optical band gaps decreased from 3.37 eV to 3.26 eV for ScxGa1-xN films, which additionally contained nanoscale lamellar inclusions of the zinc-blende phase, as revealed by aberration-corrected scanning transmission electron microscopy. Therefore, we conclude that the apparent reduction in ScxGa1-xN band gaps with increasing x is an artefact resulting from the presence of nanoscale zinc-blende inclusions. (C) 2015 AIP Publishing LLC.
引用
收藏
页数:3
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