Artificial epoxidase II. Synthesis of cyclodextrin ketoesters and epoxidation of alkenes

被引：37
作者：
Rousseau, C
Christensen, B
Bols, M
机构：
[1] Univ Aarhus, Dept Chem, DK-8000 Aarhus, Denmark
[2] Univ Aarhus, Dept Mol Biol, Prot Chem Lab, DK-8000 Aarhus, Denmark
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 13期
关键词：
artificial enzyme; oxidation; dioxirane; bridge; cyclodextrins;
D O I：
10.1002/ejoc.200500034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Four cyclodextrin ketones were synthesised and investigated as epoxidation catalysts. In the presence of oxone they catalysed the epoxidation of mono-, di- and trisubstituted alkenes in 17-100 % yield and 0-45 % ee. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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收藏
页码：2734 / 2739
页数：6
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