Hydrolysis of spirophosphoranes with a saturated 1,3,2-dioxaphosphorinane ring:: X-ray structure of the intermolecularly H-bonded phosphate ester (OCH2CMe2CH2O)P(O)(2,2′-O-C6H4-C6H4OH)

被引：14
作者：
Swamy, KCK [1 ]
Said, MA
Kumaraswamy, S
Herbst-Irmer, R
Pulm, M
机构：
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
POLYHEDRON | 1998年 / 17卷 / 20期
关键词：
spirophosphorane; phosphorinane; hydrolysis; hydrogen bonding; X-ray structure;
D O I：
10.1016/S0277-5387(98)00160-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrolysis of (6,5), (6,7) and (6,8)-spirophosphoranes containing the six-membered ring P(OCH2CMe2CH2O) has been studied; in all the cases the six-membered phosphorinane ring is retained during the first stage of hydrolysis. The X-ray structure of one such product, (OCH2CMe2CH2O) P(O)(2,2'-O-C6H4-C6H4OH) which exhibits intermolecular H-bonding, has been determined. O 1998 Elsevier Science Ltd. All rights reserved. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3643 / 3648
页数：6
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