Hydrolysis of spirophosphoranes with a saturated 1,3,2-dioxaphosphorinane ring:: X-ray structure of the intermolecularly H-bonded phosphate ester (OCH2CMe2CH2O)P(O)(2,2′-O-C6H4-C6H4OH)

被引：14

作者：

Swamy, KCK ^{[1
]}

Said, MA

Kumaraswamy, S

Herbst-Irmer, R

Pulm, M

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

POLYHEDRON | 1998年 / 17卷 / 20期

关键词：

spirophosphorane; phosphorinane; hydrolysis; hydrogen bonding; X-ray structure;

D O I：

10.1016/S0277-5387(98)00160-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrolysis of (6,5), (6,7) and (6,8)-spirophosphoranes containing the six-membered ring P(OCH2CMe2CH2O) has been studied; in all the cases the six-membered phosphorinane ring is retained during the first stage of hydrolysis. The X-ray structure of one such product, (OCH2CMe2CH2O) P(O)(2,2'-O-C6H4-C6H4OH) which exhibits intermolecular H-bonding, has been determined. O 1998 Elsevier Science Ltd. All rights reserved. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3643 / 3648

页数：6

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