Two-Dimensional Coordination Polymer {[Bi(Pyz)I3]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method

被引：9
作者：
Usoltsev, A. N. [1 ]
Adonin, S. A. [1 ,2 ,3 ,4 ]
Novikov, A. S. [5 ]
Sokolov, M. N. [1 ,3 ,6 ]
Fedin, V. P. [1 ,3 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Tyumen Ind Univ, Tobolsk Ind Inst, Tobolsk, Russia
[3] Novosibirsk Natl Res Univ, Novosibirsk 630090, Russia
[4] Southern Ural State Univ, Chelyabinsk, Russia
[5] St Petersburg State Univ, St Petersburg 199164, Russia
[6] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 01期
关键词：
bismuth; coordination polymers; pyrazine; crystal structure; analysis of Hirshfeld surfaces; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; M-II; ARCHITECTURES; COMPLEXES; NI; CL;
D O I：
10.1134/S107032842001008X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of BiI3 with pyrazine in tetrahydrofuran affords the two-dimensional coordination polymer {[Bi(Pyz)I-3]} (I), whose structure is determined by X-ray diffraction analysis (CIF file CCDC no. 1904990). The contributions of various interatomic contacts to the crystal packing of compound I are studied using the Hirshfeld surface analysis performed for the elementary unit of compound I. The interatomic distances I center dot center dot center dot H make the largest contribution to the crystal packing of compound I.
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收藏
页码：23 / 27
页数：5
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