Facile preparation of WO3/PEDOT:PSS composite for inkjet printed electrochromic window and its performance for heat shielding

被引:63
作者
Chang-Jian, Cai-Wan [1 ]
Cho, Er-Chieh [2 ]
Yen, Shih-Chieh [3 ]
Ho, Bo-Cheng [3 ]
Lee, Kuen-Chan [4 ]
Huang, Jen-Hsien [5 ]
Hsiao, Yu-Sheng [3 ]
机构
[1] I Shou Univ, Dept Mech & Automat Engn, 1,Sec 1,Syuecheng Rd, Kaohsiung 84001, Taiwan
[2] Taipei Med Univ, Coll Pharm, Sch Pharm, Dept Clin Pharm, 250 Wuxing St, Taipei 110, Taiwan
[3] Ming Chi Univ Technol, Dept Mat Engn, 84 Gungjuan Rd, Taipei 24301, Taiwan
[4] Natl Taipei Univ Educ, Dept Sci Educ, 134,Sec 2,Heping E Rd, Taipei 106, Taiwan
[5] CPC Corp, Green Technol Res Inst, Dept Green Mat Technol, 2 Zuonan Rd, Kaohsiung 81126, Taiwan
关键词
Electrochromic; WO3; PEDOT:PSS; Inkjet printing; Device; Smart window; PEDOT-PSS; FILM; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); DEPOSITION; DIIMIDES; POLYMERS; LAYER;
D O I
10.1016/j.dyepig.2017.09.026
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, we have prepared an electrochromic (EC) ink composed of WO3 nanoparticles and poly (3,4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS). The ink formulation can be processed through inkjet-printing or spray coating to deposit high-quality EC layers. The PEDOT:PSS acts as an conductive binder to connect the WO3 nanoparticles leading to reduced impedance and better electrochemical properties. The WO3/PEDOT:PSS (PH1000) exhibits an optical modulation of 54.1%, a response time of 1.1 s, and a coloration efficiency of 83.87 cm(2)/C. A hybrid type electrochromic device (ECD) incorporated with WO3/PEDOT:PSS with excellent durability has been fabricated. The performance of WO3/PEDOT:PSS based ECD for sun shielding property is also evaluated. The ECD can efficiently block the sunlight and reduce solar heat gain. As a result, the indoor temperature can be modulated from 32.7 degrees C (bleached state) to 29.4 degrees C (darken state) under illumination. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:465 / 473
页数:9
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