One-Dimensional Zinc-Based Coordination Polymer as a Higher Capacity Anode Material for Lithium Ion Batteries

被引：57

作者：

Song, Yidan ^{[1
,2
]}

Yu, Lili ^{[1
,2
]}

Gao, Yuanrui ^{[3
]}

Shi, Changdong ^{[1
,2
]}

Cheng, Meiling ^{[1
,2
]}

Wang, Xianmei ^{[1
,2
]}

Liu, Hong-Jiang ^{[3
]}

Liu, Qi ^{[1
,2
,4
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, 1 Gehu Rd, Changzhou 213164, Jiangsu, Peoples R China

[2] Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, 1 Gehu Rd, Changzhou 213164, Jiangsu, Peoples R China

[3] Shanghai Univ, Dept Chem, Coll Sci, 99 Shangda Rd, Shanghai 200444, Peoples R China

[4] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 19期

关键词：

METAL-ORGANIC FRAMEWORK; LIGAND REDOX ACTIVITIES; CRYSTAL-STRUCTURES; ENERGY-STORAGE; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; MAGNETIC-PROPERTIES; COMPLEXES; SUPERCAPACITORS; LUMINESCENCE;

D O I：

10.1021/acs.inorgchem.7b01441

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zinc-based one-dimensional (1D) coordination polymer ([Zn-(H(2)mpca)(2)(tfbdc)(H2O)], Zn-ODCP) has been synthesized and characterized by spectroscopic and physicochemical methods, single-crystal X-ray diffraction, and thermogravimetric analysis (H(2)mpca = 3-methyl-1H-pyrazole-4-carboxylic acid; H(2)tfbdc = 2,3,5,6-tetrafluoroterephthalic acid). Zn-ODCP shows blue luminescence in the solid state. When Zn-ODCP acts as an anode material for lithium ion batteries, it exhibits a good cyclic stability and a higher reversible capacity of 300 mAh g(-1) at 5O mA g(-1) after 50 cycles. The higher capacity may be mainly ascribed to the metal ion and ligand all taking part in lithium storage. Searching for electrode materials of lithium ion batteries from 1D metal coordination polymers is a new route.

引用

页码：11603 / 11609

页数：7

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