Reverse reactivity in hydroxylation of adamantane and epoxidation of cyclohexene catalyzed by the mononuclear ruthenium-oxo complexes with 6-substituted tripodal polypyridine ligands

被引：34

作者：

Jitsukawa, K ^{[1
]}

Oka, Y ^{[1
]}

Einaga, H ^{[1
]}

Masuda, H ^{[1
]}

机构：

[1] Nagoya Inst Technol, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 20期

关键词：

ruthenium and compounds; hydroxylation; epoxidation;

D O I：

10.1016/S0040-4039(01)00379-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electronic character of the ruthenium complexes with tripodal polypyridine ligands, which is controlled by the substituted groups at pyridine 6-position, gives rise to differences in the reactivity for the ruthenium catalyzed hydroxylation of adamantane and epoxidation of cyclohexene with PhIO as an oxidant; Ru complexes containing electron-withdrawing groups (1, 3, and 5) promote the epoxidation, while those containing electron-donating groups (2, 4, and 6) promote the hydroxylation. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3467 / 3469

页数：3

共 21 条

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