Interfacial tension between CO2 and brine (NaCl + CaCl2) at elevated pressures and temperatures: The additive effect of different salts

被引:115
作者
Aggelopoulos, C. A. [1 ]
Robin, M. [1 ]
Vizika, O. [1 ]
机构
[1] IFP Energies Nouvelles, F-92852 Rueil Malmaison, France
关键词
CO2; storage; Interfacial tension; Brine; Cations; Saline aquifers; CARBON-DIOXIDE; AQUEOUS-SOLUTIONS; SURFACE-TENSION; ION HYDRATION; WATER; STORAGE; PRESSURE; SEQUESTRATION; TEMPERATURE; SOLUBILITY;
D O I
10.1016/j.advwatres.2011.01.007
中图分类号
TV21 [水资源调查与水利规划];
学科分类号
081501 ;
摘要
An extensive laboratory study was conducted to measure the interfacial tension (IFT) between CO2 and brine consisting in equal molal concentrations of NaCl and CaCl2. The experiments were repeated at various pressures, temperatures and salinities that are representative of conditions prevailing during CO2 storage in deep saline aquifers. The dependence of CO2/brine IFT on pressure and temperature is similar to that previously reported for the systems: CO2/NaCl solution and CO2/CaCl2 solution. CO2/brine IFT increases linearly with water salinity and the magnitude of this increase was found equal to the sum of the individual CO2/NaCl solution and CO2/CaCl2 solution IFT increments, indicating a strong additive effect on IFT when the brine is composed of various salts. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:505 / 511
页数:7
相关论文
共 35 条
[1]  
ABRAMZON AA, 1993, RUSS J APPL CHEM+, V66, P1473
[2]   CO2/CaCl2 solution interfacial tensions under CO2 geological storage conditions: Influence of cation valence on interfacial tension [J].
Aggelopoulos, C. A. ;
Robin, M. ;
Perfetti, E. ;
Vizika, O. .
ADVANCES IN WATER RESOURCES, 2010, 33 (06) :691-697
[3]   Geologic factors controlling CO2 storage capacity and permanence:: case studies based on experience with heterogeneity in oil and gas reservoirs applied to CO2 storage [J].
Ambrose, W. A. ;
Lakshminarasimhan, S. ;
Holtz, M. H. ;
Nunez-Lopez, V. ;
Hovorka, S. D. ;
Duncan, I. .
ENVIRONMENTAL GEOLOGY, 2008, 54 (08) :1619-1633
[4]  
ARGAUD MJ, 1992 EUR COR AN S PA
[5]  
AVEYARD R, 1977, J C FARADAY, V73, P1609
[6]   Interfacial Tension between CO2, Freshwater, and Brine in the Range of Pressure from (2 to 27) MPa, Temperature from (20 to 125) °C, and Water Salinity from (0 to 334 000) mg.L-1 [J].
Bachu, Stefan ;
Bennion, D. Brant .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (03) :765-775
[7]   Interfacial tension measurements and wettability evaluation for geological CO2 storage [J].
Chalbaud, C. ;
Robin, M. ;
Lombard, J-M ;
Martin, F. ;
Egermann, P. ;
Bertin, H. .
ADVANCES IN WATER RESOURCES, 2009, 32 (01) :98-109
[8]   CO2/water interfacial tensions under pressure and temperature conditions of CO2 geological storage [J].
Chiquet, Pierre ;
Daridon, Jean-Luc ;
Broseta, Daniel ;
Thibeau, Sylvain .
ENERGY CONVERSION AND MANAGEMENT, 2007, 48 (03) :736-744
[9]   INTERFACIAL-TENSION IN HIGH-PRESSURE CARBON-DIOXIDE MIXTURES [J].
CHUN, BS ;
WILKINSON, GT .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (12) :4371-4377
[10]   Investigation of CO2 Plume Behavior for a Large-Scale Pilot Test of Geologic Carbon Storage in a Saline Formation [J].
Doughty, Christine .
TRANSPORT IN POROUS MEDIA, 2010, 82 (01) :49-76