(2SR,8aSR)-1,2,3,4,6,7,8,8a-octahydro-6-oxonaphthalene-2-acetic acid:: hydrogen bonding in an unsaturated bicyclic keto acid

被引：1

作者：

Malak, Muhammad H. ^{[1
]}

Desai, Janish ^{[1
]}

Lalancette, Roger A. ^{[1
]}

Thompson, Hugh W. ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem, Carl A Olson Mem Labs, Newark, NJ 07102 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807035003

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title racemate, C12H16O3, aggregates in the solid state as translational acid-to-ketone hydrogen-bonded catemers. The stereochemistry of the side chain relative to the ring junction arises spontaneously during the synthesis. The four hydrogen-bonding chains passing through the unit cell are of alternating handedness, and are aligned along the [101] direction. Starting at the origin, the order of the directional alignment of these four chains with respect to the a axis is ++--. One intermolecular C-H center dot center dot center dot O = C close contact exists to the carboxyl O atom.

引用

页码：O3606 / U4406

页数：10

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