INFLUENCE OF THE POROUS STRUCTURE OF V2O5-ZrO2-SiO2 CATALYST ON REACTION OF PROPANE DEHYDROGENATION

被引:0
作者
Redkina, Antonina [1 ]
Konovalova, Nadezhda [1 ]
Kravchenko, Nikolay [1 ]
Strelko, Volodymyr [1 ]
机构
[1] NAS Ukraine, Inst Sorpt & Problem Endoecol, 13,Gen Naumov Str, UA-03164 Kiev, Ukraine
来源
CHEMISTRY & CHEMICAL TECHNOLOGY | 2022年 / 16卷 / 02期
关键词
propane dehydrogenation; propylene; vanadium oxide; zirconium silicates; OXIDATIVE DEHYDROGENATION; ZIRCONIA CATALYSTS; STABILITY; SURFACE; ZRO2; SELECTIVITY; SUPPORT;
D O I
10.23939/chcht16.02.259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A spherically granular, amorphous, mesoporous catalyst was obtained by supporting V2O5 on synthesized by direct sol-gel method of ZrO2-SiO2 hydrogel and was identified by SEM, XRD and N-2 adsorption / desorption. It is shown that its hydrothermal and alcohol treatment increases the specific surface, volume and width of pores and leads to an increase in the yield of propylene in the reaction of propane dehydrogenation and decreases the temperature of reaching its high values.
引用
收藏
页码:259 / 266
页数:8
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