Cu/Picolinamides-Catalyzed Coupling of (Hetero)aryl Halides with Secondary Phosphine Oxides and Phosphite†

被引：8

作者：

Fang, Chao ^{[1
]}

Wei, Bangguo ^{[1
]}

Ma, Dawei ^{[2
]}

机构：

[1] Fudan Univ, Sch Pharm, Dept Nat Med, 826 Zhangheng Rd, Shanghai 201203, Peoples R China

[2] Univ Chinese Acad Sci, Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem,State Key Lab Bioorgan, 345 Lingling Lu, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2021年 / 39卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Synthetic methods; Cross-Coupling; Aryl halides; Copper; Aryl phosphine oxides; P BOND FORMATION; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; ARYL HALIDES; CHLORIDES; ARYLATION; DIPHENYLPHOSPHINE; PHOSPHORYLATION; BROMIDES;

D O I：

10.1002/cjoc.202100354

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Main observation and conclusion Some 4-hydroxy-picolinic acid derived amides were revealed as more efficient ligands for Cu-catalyzed coupling of (hetero)aryl halides with secondary phosphine oxides and phosphites. Only 3-5 mol% CuI and ligands were required to ensure coupling with a number of (hetero)aryl bromides and iodides to complete at 120 C-o in 10-20 h.

引用

页码：2957 / 2961

页数：5

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