Determination of quantum confinement in CdSe nanocrystals by cyclic voltammetry

被引：254

作者：

Kucur, E ^{[1
]}

Riegler, J ^{[1
]}

Urban, GA ^{[1
]}

Nann, T ^{[1
]}

机构：

[1] Freiburg Mat Res Ctr FMF, D-79104 Freiburg, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 119卷 / 04期

关键词：

D O I：

10.1063/1.1582834

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ionization potentials I(p), electron affinities E.A., and the quantum confinement in CdSe nanocrystals were determined by means of cyclic voltammetry. The results were compared to values obtained from spectroscopic measurements, especially UV/vis absorption and photoluminescence emission spectra. Absolute band gap positions were obtained from the electrochemical measurements and discussed with regard to vacuum level values. The results are in good agreement with theoretical expectations and spectroscopic data. (C) 2003 American Institute of Physics.

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页码：2333 / 2337

页数：5

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