The Simple, Effective Synthesis of Highly Dispersed Pd/C and CoPd/C Heterogeneous Catalysts via Charge-Enhanced Dry Impregnation

被引:8
作者
D'Souza, Lawrence [1 ,2 ]
Barnes, Sean [1 ]
Regalbuto, John R. [1 ,3 ]
机构
[1] Univ Illinois, Dept Chem Engn, MC 110 810 S Clinton St, Chicago, IL 60607 USA
[2] Saudi Basic Ind Corp, Corp Res & Dev, Adv Catalysis, POB 4545, Thuwal 23955, Saudi Arabia
[3] Univ S Carolina, Coll Engn & Comp, Swearingen Engn Ctr, Room 3C13,301 Main St, Columbia, SC 29208 USA
基金
美国国家科学基金会;
关键词
charge enhanced dry impregnation; CEDI; Pd/C and CoPd/C catalysts; strong electrostatic adsorption; SEA; STEM; PALLADIUM COBALT ALLOYS; SUPPORTED COBALT; REDUCTION; SURFACE; HEXANE;
D O I
10.3390/catal6050072
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pd/C and CoPd/C heterogeneous catalysts have been synthesized by adopting Charge Enhanced Dry Impregnation (CEDI). The particles size distribution, their high metal surface-to-bulk ratios, and synthesis feasibility are unmatchable to any known noble metal bimetallic heterogeneous catalyst preparation techniques. Next generation Fuel Cells and Fischer-Tropsch catalytic processes economy will be benefited from the proposed methodology.
引用
收藏
页数:11
相关论文
共 18 条
  • [1] Chorkendorff I, 2003, Concepts of modern catalysis and kinetics
  • [2] Preparation of carbon supported cobalt by electrostatic adsorption of [Co(NH3)6]Cl3
    D'Souza, L.
    Regalbuto, J. R.
    Miller, J. T.
    [J]. JOURNAL OF CATALYSIS, 2008, 254 (02) : 157 - 169
  • [3] Palladium complexes in concentrated nitrate and acid solutions
    Frias, EC
    Pitsch, H
    Ly, J
    Poitrenaud, C
    [J]. TALANTA, 1995, 42 (11) : 1675 - 1683
  • [4] He M., 2011, P 11AICHE 2011 AICHE
  • [5] THE STRUCTURE AND ACTIVITY OF SILICA-SUPPORTED PALLADIUM COBALT ALLOYS .2. SKELETAL REACTIONS OF N-HEXANE AND METHYLCYCLOPENTANE OVER PD-CO/SIO2 CATALYSTS
    JUSZCZYK, W
    KARPINSKI, Z
    PIELASZEK, J
    PAAL, Z
    [J]. JOURNAL OF CATALYSIS, 1993, 143 (02) : 583 - 593
  • [6] THE STRUCTURE AND ACTIVITY OF SILICA-SUPPORTED PALLADIUM COBALT ALLOYS .1. ALLOY HOMOGENEITY, SURFACE-COMPOSITION, AND ACTIVITY FOR NEOPENTANE CONVERSION
    JUSZCZYK, W
    KARPINSKI, Z
    LOMOT, D
    PIELASZEK, J
    PAAL, Z
    STAKHEEV, AY
    [J]. JOURNAL OF CATALYSIS, 1993, 142 (02) : 617 - 629
  • [7] Kratzer E., 2006, THESIS U ILLINOIS CH
  • [8] Reduced Graphene Oxide Supported Bimetallic Cobalt-Palladium Nanoparticles with High Catalytic Activity towards Formic Acid Electro-oxidation
    Li, Nanting
    Tang, Shaochun
    Meng, Xiangkang
    [J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2015, 31 (01) : 30 - 36
  • [9] CLASSIFICATION OF METAL CATALYSTS IN HYDROGENOLYSIS OF HEXANE ISOMERS
    MATSUMOTO, H
    SAITO, Y
    YONEDA, Y
    [J]. JOURNAL OF CATALYSIS, 1971, 22 (02) : 182 - +
  • [10] The promoting effect of noble metal addition on niobia-supported cobalt catalysts
    Noronha, FB
    Frydman, A
    Aranda, DAG
    Perez, C
    Soares, RR
    Morawek, B
    Castner, D
    Campbell, CT
    Frety, R
    Schmal, M
    [J]. CATALYSIS TODAY, 1996, 28 (1-2) : 147 - 157