Synthesis of 1,1-diacetates from aldehydes using trimethylchlorosilane and sodium iodide as catalyst

被引:56
作者
Deka, N [1 ]
Borah, R [1 ]
Kalita, DJ [1 ]
Sarma, JC [1 ]
机构
[1] Reg Res Lab, Nat Prod Chem Grp, Div Organ Chem, Jorhat 785006, Assam, India
来源
JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 02期
关键词
D O I
10.1039/a703477f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A variety of aldehydes react with acetic anhydride in the presence of trimethylchlorosilane and sodium iodide or trimethylchlorosilane alone to afford 1,1-diacetates in excellent yields.
引用
收藏
页码:94 / 95
页数:3
相关论文
共 14 条
[1]  
Bandgar BP, 1995, J CHEM RES-S, P470
[2]   Iodine as acetylation catalyst in the preparation of 1,1-diacetates from aldehydes [J].
Deka, N ;
Kalita, DJ ;
Borah, R ;
Sarma, JC .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (05) :1563-1564
[3]   ACETALS AS CROSSLINKING REAGENTS FOR COTTON [J].
FRICK, JG ;
HARPER, RJ .
JOURNAL OF APPLIED POLYMER SCIENCE, 1984, 29 (04) :1433-1447
[4]   EVIDENCE FOR A CYCLIC AA11 MECHANISM IN HYDROLYSIS OF BENZYLIDENE DIACETATES [J].
GREGORY, MJ .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (06) :1201-&
[5]   PROTECTING GROUPS IN ORGANIC-SYNTHESIS .8. CONVERSION OF ALDEHYDES INTO GEMINAL DIACETATES [J].
KOCHHAR, KS ;
BAL, BS ;
DESHPANDE, RP ;
RAJADHYAKSHA, SN ;
PINNICK, HW .
JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (10) :1765-1767
[6]  
KULA J, 1988, Patent No. 143824
[7]   AN EFFICIENT SYNTHESIS OF DIACETATES FROM ALDEHYDES USING BETA-ZEOLITE [J].
KUMAR, P ;
HEGDE, VR ;
KUMAR, TP .
TETRAHEDRON LETTERS, 1995, 36 (04) :601-602
[8]  
LEIBERMANN SV, 1955, ORG SYNTH COLL, V3, P441
[9]  
MARCH J, 1986, ADV ORG CHEM, P861
[10]  
MICHIE JK, 1981, SYNTHESIS-STUTTGART, P824