Practical Approach to Structurally Diverse Monoimine Salts and Nonsymmetrical Metallosalphen Complexes

被引：27

作者：

Escudero-Adan, Eduardo C. ^{[1
]}

Martinez Belmonte, Marta ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Kleij, Arjan W. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] ICREA, Barcelona 08010, Spain

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 20期

关键词：

SALEN; CATALYSIS; LIGANDS; ACCESS;

D O I：

10.1021/ol101898y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical approach toward the synthesis of monoimme NBu4 salts derived from Zn(salphen) complexes is described The method involves nucleophilic addition of the hydroxide anion to the imine bond followed by hydrolysis These monoimines provide accessible and useful reagents for the synthesis of (chiral) metallosalens with fine-tunable properties

引用

页码：4592 / 4595

页数：4

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