Recyclable process for sustainable adipic acid production in microemulsions

被引：40
作者：
Blach, Philippe [1 ]
Boestrom, Zebastian [1 ]
Franceschi-Messant, Sophie [1 ]
Lattes, Armand [1 ]
Perez, Emile [1 ]
Rico-Lattes, Isabelle [1 ]
机构：
[1] Univ Toulouse 3, CNRS, UMR 5623, Lab IMRCP, F-31062 Toulouse, France
来源：
TETRAHEDRON | 2010年 / 66卷 / 35期
关键词：
Microemulsion; Adipic acid; Hydrogen peroxide; Oxidation; Sustainable chemistry; LIQUID-PHASE OXIDATION; HYDROGEN-PEROXIDE; BENZALKONIUM CHLORIDE; SELECTIVE OXIDATION; CATALYTIC-OXIDATION; CLEAN SYNTHESIS; CYCLOHEXENE; H2O2; EPOXIDATION; SULFOXIDES;
D O I：
10.1016/j.tet.2010.06.093
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Adipic acid is an important industrial intermediate for the manufacture of nylon-6,6. We propose a recyclable and environmentally friendly process for the oxidation of cyclohexene by hydrogen peroxide in microemulsions. These organized nano-structured media have been formulated in using the molecular economy principle. The main interests of the present work are the easy recovery of pure adipic acid and the reuse of the reaction media, what are promising for developing a future green industrial process. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7124 / 7128
页数：5
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