EPR of Cu(II) in sarcosine cadmium chloride: probe into dopant site - symmetry and copper-sarcosine interaction

被引：8

作者：

Padiyan, DP ^{[1
]}

Muthukrishnan, C

Murugesan, R

机构：

[1] Manonmariam Sundaranar Univ, Dept Phys, Tirunelveli 627012, India

[2] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2000年 / 222卷 / 03期

关键词：

EPR; rhombic symmetry; Shf; admixture coefficients; MO coefficients;

D O I：

10.1016/S0304-8853(00)00555-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electron paramagnetic resonance spectra of Cu(IT) doped sarcosine cadmium chloride single crystals have been investigated at room temperature. Experimental results reveal that the Cu(II) ion enters the lattice interstitially. The observed superhyperfine lines indicate the superposition of two sets of quintet structure with interaction of nitrogen atoms and the two isotopes of copper. The spin Hamiltonian parameters are evaluated by Schonland method and the electric field symmetry around the copper ion is rhombic. An admixture of d(z)(2) orbital with the d(x2-y2) ground state is observed. Evaluation of MO coefficients reveals that the in-plane interaction between copper and nitrogen is strong in this lattice. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：251 / 256

页数：6

共 12 条

[1] Influence of host lattice in interstital dopant sites: EPR studies on Cu (II) doped sarcosine cadmium bromide single crystals
Padiyan, DP
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CRYSTAL RESEARCH AND TECHNOLOGY, 2000, 35 (05) : 595 - 600
[2] Single crystal EPR studies on Mn(II)-doped sarcosine cadmium chloride and sarcosine cadmium bromide: Study of zero-field splitting tensor in iso-structural complexes
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[3] EPR of Cu2+-doped tris-sarcosine calcium chloride
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MOLECULAR PHYSICS, 2009, 107 (15) : 1555 - 1562
[4] EPR studies on the effects of dopant cadmium (II) ions on the low magnetic dimensionality of copper calcium acetate hexahydrate
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Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1997, 36 (02): : 688 - 691
[5] EPR studies on the effects of dopant cadmium(II) ions on the low magnetic dimensionality of copper calcium acetate hexahydrate
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[6] DYNAMICAL EFFECTS IN EPR-SPECTRA OF CU(II) DOPED TETRA-AMMINE CADMIUM CHLORIDE AND ACETATE
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[7] Single crystal EPR of Cu(II) doped [Co(tbZ)2(NO3)(H2O)]NO3:: probe into copper-thiabendazole interaction
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[8] SINGLE-CRYSTAL EPR STUDY OF MN(II)-DOPED CIS-CATENA-MU-SULFATO-AQUOTRIS(IMIDAZOLE)CADMIUM(II) - MN(II) IN IMIDAZOLE LIGATED LOW-SYMMETRY SITE
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