Spectral study on manganese- and silver-doped lithium tetraborate phosphors

被引:33
作者
Ignatovych, M.
Holovey, V.
Vidozy, T.
Baranyai, P.
Kelemen, A.
机构
[1] NASU, Inst Surface Chem, UA-03164 Kiev, Ukraine
[2] NASU, Inst Electron Phys, UA-88000 Uzhgorod, Ukraine
[3] BUTE, Photosci Lab, H-1525 Budapest, Hungary
[4] CRC HAS, Inst Isotopes, H-1525 Budapest, Hungary
关键词
doped lithium tetraborate; manganese; silver; photoluminescence; optical absorption;
D O I
10.1016/j.radphyschem.2007.02.066
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Manganese- and silver-doped lithium tetraborate (LTB) single crystal and glassy phosphors with different dopant contents were studied. Optical absorption, steady-state and time-resolved photoluminescence (PhL) techniques were used for spectral characterization of samples. Optical absorption, as well as PhL excitation and emission spectra of LTB:Mn single crystal, revealed that manganese is present only in the form of Mn2+ ions, while in the glassy LTB:Mn simultaneous presence of Mn2+ and Mn3+ ions was detected. Optical absorption and PhL spectral characterization of LTB:Ag single crystal showed that only one type of Ag1+ ions are absorbing and emitting centers while in the LTB:Ag glassy samples the presence of at least two non-equivalent surrounding of Ag1+ ions was revealed. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1527 / 1530
页数:4
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