High-resolution laser excitation spectra of the A2Π←X2Σ+ system of SrBr:: The 0-0 and 1-0 bands of Sr79Br and Sr81Br

被引：6
作者：
Coxon, JA [1 ]
Dickinson, CS [1 ]
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1998年 / 190卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1006/jmsp.1998.7586
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Two bands (0-0 and 1-0) of the A(2)Pi-X(2)Sigma(+) system of (SrBr)-Sr-88-Br-79 and (SrBr)-Sr-88-Br-81 have been analyzed rotationally for the first time. Well-resolved spectra were recorded by laser excitation spectroscopy with selective detection of fluorescence. For each band of the individual isotopomers, about 130 Line positions with a measurement accuracy of approximate to 0.003 cm(-1) were employed in a least-squares ft of the excited stare molecular parameters. The principal results for the A(2)Pi state are A(e) = 302.432(1) cm(-1) and R-e = 2.7147(1) Angstrom. (C) 1998 Academic Press.
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页码：150 / 156
页数：7
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