The 2Ag- energies of all-trans-neurosporene and spheroidene as determined by fluorescence spectroscopy

被引:100
作者
Fujii, R
Onaka, K
Kuki, M
Koyama, Y [1 ]
Watanabe, Y
机构
[1] Kwansei Gakuin Univ, Fac Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
[2] Kwansei Gakuin Univ, Fac Sci, Dept Phys, Nishinomiya, Hyogo 6628501, Japan
[3] Kobe City Coll Technol, Dept Appl Chem, Nishi Ku, Kobe, Hyogo 6512194, Japan
关键词
D O I
10.1016/S0009-2614(98)00376-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fluorescence spectra of neurosporene and spheroidene were recorded in order to determine their 2A(g)(-) levels: each fluorescence spectrum was deconvoluted into two series of 1B(u)(+) -->1A(g)(-) and 2A(g)(-) --> 1A(g)(-) vibronic transitions, and the energy of the 2A(g)(- )(upsilon = 0) state was determined to be 15300 cm(-1) in neurosporene and 14200 cm(-1) in spheroidene. No temperature dependence of these energies was seen. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:847 / 853
页数:7
相关论文
共 22 条
[1]   DUAL SINGLET-STATE EMISSION IN A SERIES OF MINI-CAROTENES [J].
ANDERSSON, PO ;
GILLBRO, T ;
ASATO, AE ;
LIU, RSH .
JOURNAL OF LUMINESCENCE, 1992, 51 (1-3) :11-20
[2]   SOLVENT AND TEMPERATURE EFFECTS ON DUAL FLUORESCENCE IN A SERIES OF CAROTENES - ENERGY-GAP DEPENDENCE OF THE INTERNAL-CONVERSION RATE [J].
ANDERSSON, PO ;
BACHILO, SM ;
CHEN, RL ;
GILLBRO, T .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (44) :16199-16209
[3]   TEMPERATURE AND VISCOSITY SENSITIVE S-1 EMISSION FROM A HIGHLY SUBSTITUTED TRIENE [J].
ANDERSSON, PO ;
GILLBRO, T ;
ASATO, AE ;
LIU, RSH .
CHEMICAL PHYSICS LETTERS, 1995, 235 (1-2) :76-82
[4]   THE APPLICATION OF THE ENERGY-GAP LAW TO THE S-1 ENERGIES AND DYNAMICS OF CAROTENOIDS [J].
CHYNWAT, V ;
FRANK, HA .
CHEMICAL PHYSICS, 1995, 194 (2-3) :237-244
[5]   LOW-LYING ELECTRONIC STATES OF CAROTENOIDS [J].
DECOSTER, B ;
CHRISTENSEN, RL ;
GEBHARD, R ;
LUGTENBURG, J ;
FARHOOSH, R ;
FRANK, HA .
BIOCHIMICA ET BIOPHYSICA ACTA, 1992, 1102 (01) :107-114
[6]  
Frank H. A., 1993, CAROTENOIDS PHOTOSYN, P253
[7]   Spectroscopic properties of spheroidene analogs having different extents of pi-electron conjugation [J].
Frank, HA ;
Desamero, RZB ;
Chynwat, V ;
Gebhard, R ;
vanderHoef, I ;
Jansen, FJ ;
Lugtenburg, J ;
Gosztola, D ;
Wasielewski, MR .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (02) :149-157
[8]   LOCATION OF THE CAROTENOID 2A(G)-STATE AND ITS ROLE IN PHOTOSYNTHESIS [J].
GILLBRO, T ;
ANDERSSON, PO ;
LIU, RSH ;
ASATO, AE ;
TAKAISHI, S ;
COGDELL, RJ .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1993, 57 (01) :44-48
[9]  
Jiang YS, 1996, BIOSPECTROSCOPY, V2, P47, DOI 10.1002/(SICI)1520-6343(1996)2:1<47::AID-BSPY5>3.0.CO
[10]  
2-P