N-methylpiperidine - A useful base catalyst in the Morita-Baylis-Hillman reaction

被引:5
|
作者
Zhao, SH
Chen, ZB [1 ]
机构
[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
[2] Xinzhou Teachers Univ, Xinzhou, Peoples R China
关键词
aldehyde; base catalyst; Morita-Baylis-Hillman reaction; dioxane-water; N-methylpiperidine;
D O I
10.1080/00397910500278776
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
N-methylpiperidine, a commercially available mild base, has effectively been utilized as a catalyst in the Morita-Baylis-Hillman reaction. Moderate to excellent yields (34-95%) and significant rate enhancement have been observed.
引用
收藏
页码:3045 / 3053
页数:9
相关论文
共 50 条
  • [1] Acceleration of the Morita-Baylis-Hillman Reaction by a Simple Mixed Catalyst System
    Bugarin, Alejandro
    Connell, Brian T.
    JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (12): : 4638 - 4641
  • [2] Dual catalyst control in the enantioselective intramolecular Morita-Baylis-Hillman reaction
    Aroyan, CE
    Vasbinder, MM
    Miller, SJ
    ORGANIC LETTERS, 2005, 7 (18) : 3849 - 3851
  • [3] A highly active ionic liquid catalyst for Morita-Baylis-Hillman reaction
    Lin, YS
    Lin, CY
    Liu, CW
    Tsai, TYR
    TETRAHEDRON, 2006, 62 (05) : 872 - 877
  • [4] Sila Morita-Baylis-Hillman reaction of cyclopropenes
    Chuprakov, Stepan
    Malyshev, Denis A.
    Trofimov, Alexander
    Gevorgyan, Vladimir
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (48) : 14868 - 14869
  • [5] Nicholas cations in the Morita-Baylis-Hillman reaction
    Campbell, Mark
    Krafft, Marie E.
    Kerrigan, Sean
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [6] Recent extensions of the Morita-Baylis-Hillman reaction
    Ma, Guang-Ning
    Jiang, Jia-Jun
    Shi, Min
    Wei, Yin
    CHEMICAL COMMUNICATIONS, 2009, (37) : 5496 - 5514
  • [7] Asymmetric organocatalytic Morita-Baylis-Hillman reaction and asymmetric organocatalytic transformations of Morita-Baylis-Hillman adducts. An update
    Pellissier, Helene
    TETRAHEDRON, 2025, 172
  • [8] Privileged chiral catalysts in asymmetric Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman reaction
    Wei Yin
    Shi Min
    CHINESE SCIENCE BULLETIN, 2010, 55 (17): : 1699 - 1711
  • [9] Guanidine/Azole Binary System as an Efficient Catalyst for Morita-Baylis-Hillman Reaction
    Terada, Masahiro
    Fukuchi, Satoko
    Amagai, Kei
    Nakano, Megumi
    Ube, Hitoshi
    CHEMCATCHEM, 2012, 4 (07) : 963 - 967
  • [10] Toward the development of an asymmetric Morita-Baylis-Hillman reaction
    Lin, YM
    Boucau, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3441 - U3441