Synthesis and characterizations of poly(α-naphthylamine)-nanocomposites

被引：12

作者：

Anbarasan, R. ^{[1
]}

Anandhakrishnan, R. ^{[1
]}

Vivek, G. ^{[1
]}

机构：

[1] Kamaraj Coll Engn & Technol, Adv Nanotechnol Res Lab, Dept Polymer Technol, Virudunagar 626001, Tamil Nadu, India

来源：

POLYMER COMPOSITES | 2008年 / 29卷 / 09期

关键词：

D O I：

10.1002/pc.20462

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Poly(alpha-naphthylamine) (PNA)-natural clay nanocomposites were prepared by in situ polymerization method through oxidative initiation method. Effect of nanoclay on the rate of polymerization (R-p) of Naphthylamine (NA), thermal stability of PNA, and conductivity of PNA were tested. Effect of nanoclay on the morphology of PNA was also tested. The TGA results inferred that the % weight residue remain above 700 degrees C was increased with the increase of amount of clay. XRD results confirmed the intercalation of PNA into the basal spacing of natural clay. TEM showed the presence of nanosized particle in the PNA-natural clay nanocomposites. The conductivity value of polymer-nanocomposite has increased with the increase of amount of natural clay.

引用

页码：949 / 953

页数：5

共 12 条

[1]

Anbarasan R., 2006, INT J POLYMERIC MAT, V55, P803, DOI [10.1080/00914030500496023, DOI 10.1080/00914030500496023]

[2] MECHANISM OF ELECTROPOLYMERIZATION OF 1-NAPHTHYLAMINE IN AQUEOUS ACID-MEDIA [J].

AREVALO, AH ;

FERNANDEZ, H ;

SILBER, JJ ;

SERENO, L .

ELECTROCHIMICA ACTA, 1990, 35 (04) :741-748

[3] High yield polymerisation of aniline and pyrrole in presence of montmorillonite clay and formation of nanocomposites thereof [J].

Ballav, N ;

Biswas, M .

POLYMER JOURNAL, 2004, 36 (02) :162-166

[4] Structure and stereochemistry of electrochemically synthesized poly-(1-naphthylamine) from neutral acetonitrile solution [J].

Ciric-Marjanovic, G ;

Marjanovic, B ;

Stamenkovic, V ;

Vitnik, Z ;

Antic, V ;

Juranic, I .

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2002, 67 (12) :867-877

[5]

Ciric-Marjanovic G, 2004, MATER SCI FORUM, V453-454, P139, DOI 10.4028/www.scientific.net/MSF.453-454.139

[6] Electrochemical synthesis and structure of poly(2-methyl-1-naphthylamine) films [J].

Ciric-Marjanovic, G ;

Cvjeticanin, N ;

Mentus, S .

SPECTROSCOPY LETTERS, 2003, 36 (1-2) :151-165

[7]

DHAVAN SK, 1992, J APPL ELECTROCHEM, V22, P563

[8] OXIDATION OF 2,5-DIMETHYLANILINE IN NH4F.2.35 HF MEDIUM - CHARACTERISTICS OF THE RESULTING CONDUCTING POLYMER [J].

GENIES, EM ;

NOEL, P .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 296 (02) :473-490

[9] Electrochemical properties of poly-1-naphthylamine synthesized in the presence of ferrocenesulfonic acid [J].

Li, X ;

Sun, C ;

Wei, ZB .

SYNTHETIC METALS, 2005, 155 (01) :45-50

[10] SYNTHESIS OF POLY(1-AMINONAPHTHALENE) AND POLY(1-AMINOANTHRACENE) BY CHEMICAL OXIDATIVE POLYMERIZATION AND CHARACTERIZATION OF THE POLYMERS [J].

MOON, DK ;

OSAKADA, K ;

MARUYAMA, T ;

KUBOTA, K ;

YAMAMOTO, T .

MACROMOLECULES, 1993, 26 (25) :6992-6997

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