Effect of the introduction of alkaline promoters into chromium oxide catalysts for propane dehydrogenation in the presence of CO2

被引：6

作者：

Lapidus, A. L. ^{[1
]}

Agafonov, Yu. A. ^{[1
]}

Gaidai, N. A. ^{[1
]}

Trushin, D. V. ^{[1
]}

Nekrasov, N. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

SOLID FUEL CHEMISTRY | 2012年 / 46卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

OXIDATIVE DEHYDROGENATION; PERFORMANCE; PROPYLENE; CR/SIO2; ETHANE;

D O I：

10.3103/S0361521912010089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of the introduction of alkaline promoters into chromium oxide catalysts for the dehydrogenation of propane in the presence of CO2 was investigated. The positive role of potassium, which manifested itself in an increase in the selectivity and stability of catalysts, was shown. It was established by IR spectroscopy that, in the chromium oxide catalysts where a substantial part of protons is replaced by an alkaline ion, a decrease in their activity and stability in the dehydrogenation of propane in the presence of CO2 was observed.

引用

页码：14 / 22

页数：9

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