Mixed Picolinate and Quinaldinate Iron(III) Complexes for the Catalytic Oxidation of Alcohols with Hydrogen Peroxide

被引：8

作者：

Tanaka, Shinji ^{[1
]}

Kon, Yoshihiro ^{[1
]}

Ogawa, Atsuko ^{[1
]}

Uesaka, Yumiko ^{[1
]}

Tamura, Masanori ^{[1
]}

Sato, Kazuhiko ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, Cent 5,Higashi 1-1-1, Tsukuba, Ibaraki, Japan

来源：

CHEMCATCHEM | 2016年 / 8卷 / 18期

关键词：

catalysis; hydrogen peroxide; iron; oxidation; practical synthesis; PEROXOCARBONATE LIGAND; IRON COMPLEX; METAL; H2O2; HYDROCARBONS; EPOXIDATION; EFFICIENT; SYSTEMS; ACID; HYDROXYLATION;

D O I：

10.1002/cctc.201600362

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of Fe mixed picolinate and quinaldinate complexes that catalyze the H2O2 oxidation of alcohols are presented. The Fe catalysts are generated in situ by simple mixing of iron acetate with 6-methylpicolinic acid (6-MepicH) and 4-chloropicolinic acid (4-ClpicH); they showed high catalytic activity for H2O2 oxidation of 1-phenylethanol to acetophenone. Fe complexes generated in situ as precatalysts were successfully isolated and structurally characterized. Based on the single-crystal X-ray analysis and electrochemical measurements of the Fe complexes, the lability of picolinate and/or quinaldinate ligand and the redox potential of Fe-III were found to be important factors for the catalytic reaction.

引用

页码：2930 / 2938

页数：9

共 50 条

[1] Catalytic oxidation of alcohols to carbonyl compounds with hydrogen peroxide using dinuclear iron complexes
Balogh-Hergovich, É
Speier, G
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 230 (1-2) : 79 - 83
[2] Oxidation of aromatic compounds by hydrogen peroxide catalyzed by mononuclear iron(III) complexes
Silva, Giselle C.
Carvalho, Nakedia M. F.
Horn, Adolfo, Jr.
Lachter, Elizabeth R.
Antunes, Octavio A. C.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2017, 426 : 564 - 571
[3] Chemoselective hydrogen peroxide oxidation of allylic and benzylic alcohols under mild reaction conditions catalyzed by simple iron-picolinate complexes
Tanaka, Shinji
Kon, Yoshihiro
Nakashima, Takuya
Sato, Kazuhiko
RSC ADVANCES, 2014, 4 (71): : 37674 - 37678
[4] Selective oxidation of alcohols with hydrogen peroxide catalyzed by hexadentate binding 8-quinolinolato manganese(III) complexes
Ye, Zhengpei
Fu, Zaihui
Zhong, Sheng
Xie, Fang
Zhou, Xiaoping
Liu, Fenglan
Yin, Dulin
JOURNAL OF CATALYSIS, 2009, 261 (01) : 110 - 115
[5] Oxidation of alcohols with hydrogen peroxide catalyzed by supported Fe(III) porphyrins
Masoudian, Shahla
Yahyaei, Hooriye
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2011, 50 (07): : 1002 - 1005
[6] Oxidation of Benzylic Alcohols with Urea-Hydrogen Peroxide and Catalytic Magnesium Bromide
Park, Hee Joong
Lee, Jong Chan
SYNLETT, 2009, (01) : 79 - 80
[7] Catalytic oxidation of cyclic hydrocarbons with hydrogen peroxide using Fe complexes immobilized into montmorillonite
Yamaguchi, Syuhei
Ihara, Daijiro
Yamashita, Yuki
Uemoto, Yudai
Yahiro, Hidenori
CATALYSIS TODAY, 2020, 352 : 243 - 249
[8] Catalytic oxidation of alcohols and sulfides with hydrogen peroxide using isoindoline and phthalazine-based diiron complexes
Szavuly, Miklos
Szilvasi, Szilvio D.
Csonka, Robert
Klesitz, Daniel
Speier, Gabor
Giorgi, Michel
Kaizer, Jozsef
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 393 : 317 - 324
[9] Bismuth Tribromide Catalyzed Oxidation of Alcohols with Aqueous Hydrogen Peroxide
Han, Mi-kyung
Kim, Sohwa
Kim, Sung Tae
Lee, Jong Chan
SYNLETT, 2015, 26 (17) : 2434 - 2436
[10] Green oxidation of alcohols with hydrogen peroxide catalyzed by a tetra-cobalt polyoxometalate in water
Farsani, Mostafa Riahi
Assady, Elham
Jalilian, Fariba
Yadollahi, Bahram
Rudbari, Hadi Amiri
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2015, 12 (07) : 1207 - 1212

← 1 2 3 4 5 →