Rhodium-catalyzed direct ortho C-H olefination of phenol derivatives

被引：103
|
作者：
Feng, Chao [1 ]
Loh, Teck-Peng [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637616, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 37期
关键词：
OXIDATIVE COUPLING REACTION; BOND FUNCTIONALIZATION; ACTIVATION; ALKENYLATION; REACTIVITY; ACID; EFFICIENT; ANILIDES; BENZENES; INDOLES;
D O I：
10.1039/c1cc14108b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an alpha,beta-unsaturated ester appendage is described. In addition, deuterium labelling and kinetic isotope effect studies were performed to probe the reaction mechanism.
引用
收藏
页码：10458 / 10460
页数：3
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