Rhodium-catalyzed direct ortho C-H olefination of phenol derivatives

被引：103

作者：

Feng, Chao ^{[1
]}

Loh, Teck-Peng ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637616, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 37期

关键词：

OXIDATIVE COUPLING REACTION; BOND FUNCTIONALIZATION; ACTIVATION; ALKENYLATION; REACTIVITY; ACID; EFFICIENT; ANILIDES; BENZENES; INDOLES;

D O I：

10.1039/c1cc14108b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an alpha,beta-unsaturated ester appendage is described. In addition, deuterium labelling and kinetic isotope effect studies were performed to probe the reaction mechanism.

引用

页码：10458 / 10460

页数：3

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