A review of microphase separation of polyurethane: Characterization and applications

被引：193

作者：

Cheng, Bing-Xu ^{[1
]}

Gao, Wei-Chen ^{[1
]}

Ren, Xiao-Ming ^{[2
]}

Ouyang, Xin-Yi ^{[1
]}

Zhao, Yuan ^{[1
]}

Zhao, Hui ^{[1
,2
]}

Wu, Wei ^{[3
]}

Huang, Chong-Xing ^{[1
]}

Liu, Yang ^{[1
]}

Liu, Xiao-Yang ^{[4
]}

Li, Hua-Nan ^{[2
]}

Li, Robert K. Y. ^{[3
]}

机构：

[1] Guangxi Univ, Coll Light Ind & Food Engn, Nanning 530004, Peoples R China

[2] Hubei Univ, State Key Lab Biocatalysis & Enzyme Engn, Key Lab Green Preparat & Applicat Funct Mat, Wuhan 430062, Peoples R China

[3] City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, Tat Chee Ave, Hong Kong, Peoples R China

[4] SUNY Stony Brook, Stony Brook, NY 11790 USA

来源：

POLYMER TESTING | 2022年 / 107卷

关键词：

Microphase separation; Polyurethane; Properties; Hydrogen bond; SEGMENTED POLYURETHANES; MECHANICAL-PROPERTIES; PHASE-SEPARATION; MORPHOLOGY; ELASTOMER; FILMS; ENHANCEMENT; TEMPERATURE; NANOSCALE; URETHANE);

D O I：

10.1016/j.polymertesting.2022.107489

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The microphase separation of polyurethane is the result of thermodynamic incompatibility between the hard and soft segments, which plays a significant role in its micro structure and performance. In recent years, many researches about the microphase separation of polyurethane have been reported. However, there is a gap in summarizing the recent advances in the characterization methods and applications about it. To fill in this gap, this paper carefully compared and analyzed the characterization methods of the microphase separation such as Fourier transform infrared spectroscopy (FT-IR), Differential scanning calorimetry (DSC), Dynamic thermomechanical analyzer (DMA), Atomic force microscopy (AFM), Transmission electron microscopy (TEM), and Small-angle X-ray scattering (SAXS). Moreover, applicaitions of the microphase separated polyurethane in shape memory, water resistance, and gas separation are also discussed in detail.

引用

页数：10

共 66 条

[1] Acoustic damping flexible polyurethane foams: Effect of isocyanate index and water content on the soundproofing [J].

Baghban, Sahar Abdollahi ;

Khorasani, Manouchehr ;

Sadeghi, Gity Mir Mohamad .

JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (15)

[2] Soundproofing flexible polyurethane foams: The impact of polyester chemical structure on the microphase separation and acoustic damping [J].

Baghban, Sahar Abdollahi ;

Khorasani, Manouchehr ;

Sadeghi, Gity Mir Mohamad .

JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (46)

[3] Clarifying the Origin of Multiple Melting of Segmented Thermoplastic Polyurethanes by Fast Scanning Calorimetry [J].

Balko, J. ;

Fernandez-d'Arlas, B. ;

Poeselt, E. ;

Dabbous, R. ;

Mueller, A. J. ;

Thurn-Albrecht, T. .

MACROMOLECULES, 2017, 50 (19) :7672-7680

[4] Elasticity and inelasticity of thermoplastic polyurethane elastomers: Sensitivity to chemical and physical structure [J].

Buckley, C. P. ;

Prisacariu, C. ;

Martin, C. .

POLYMER, 2010, 51 (14) :3213-3224

[5] Preparation, Characterization, and Mechanism for Biodegradable and Biocompatible Polyurethane Shape Memory Elastomers [J].

Chien, Yu-chun ;

Chuang, Wei-Tsung ;

Jeng, U. -Ser ;

Hsu, Shan-hui .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (06) :5419-5429

[6] Electron beam irradiation effect on the mechanical properties of nanosilica-filled polyurethane films [J].

Dong, Fei ;

Maganty, Suraj ;

Meschter, Stephan J. ;

Nozaki, Shinji ;

Ohshima, Takeshi ;

Makino, Takahiro ;

Cho, Junghyun .

POLYMER DEGRADATION AND STABILITY, 2017, 141 :45-53

[7] Structural development during deformation of polyurethane containing polyhedral oligomeric silsesquioxanes (POSS) molecules [J].

Fu, BX ;

Hsiao, BS ;

Pagola, S ;

Stephens, P ;

White, H ;

Rafailovich, M ;

Sokolov, J ;

Mather, PT ;

Jeon, HG ;

Phillips, S ;

Lichtenhan, J ;

Schwab, J .

POLYMER, 2001, 42 (02) :599-611

[8] Microphase-separated, hierarchical macroporous polyurethane from a nonaqueous emulsion-templated reactive block copolymer [J].

Gui, Haoguan ;

Guan, Guangwu ;

Zhang, Tao ;

Guo, Qipeng .

CHEMICAL ENGINEERING JOURNAL, 2019, 365 :369-377

[9] Asynchronous fracture of hierarchical microstructures in hard domain of thermoplastic polyurethane elastomer: Effect of chain extender [J].

Guo, Yaqian ;

Zhang, Ruoyu ;

Xiao, Qiang ;

Guo, Hongxia ;

Wang, Zongbao ;

Li, Xing ;

Chen, Jing ;

Zhu, Jin .

POLYMER, 2018, 138 :242-254

[10] Enhancement of microphase ordering and mechanical properties of supramolecular hydrogen-bonded polyurethane networks [J].

Hermida-Merino, Daniel ;

O'Driscoll, Ben ;

Hart, Lewis R. ;

Harris, Peter J. ;

Colquhoun, Howard M. ;

Slark, Andrew T. ;

Prisacariu, Cristina ;

Hamley, Ian W. ;

Hayes, Wayne .

POLYMER CHEMISTRY, 2018, 9 (24) :3406-3414

← 1 2 3 4 5 6 7 →