Synthesis and spectroscopic properties of a series of new tetra-substituted metal phthalocyanines

被引:7
作者
Yu Hai-ling [1 ]
Yang Jin [1 ]
Fu Qiang [1 ]
Ma Ii-cheng [1 ]
Ll Wei-li [1 ]
机构
[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
关键词
metal phthalocyanines; soluble; 8-quinolinol; UV-Vis spectrum;
D O I
10.1016/S1005-9040(08)60026-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new class of metal phthalocyanines(MPcs) containing four 8-quinolinol(8-QH) derivative moieties were successfully synthesized and characterized by mass spectroscopy, IR, UV-Vis and element analysis, the results of which were consistent with the proposed structures. All of them can dissolve in common organic solvents, such as dichloromethane, chloroform, and acetone. The effect of metal ion on the absorption of Q band was studied with UV-Vis spectra. The fluorescent properties for those complexes were also investigated.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 30 条
[1]   Synthesis and characterization of novel symmetrical phthalocyanines substituted with four benzo[d] [1,3] dioxol-5-ylmethoxy groups [J].
Agirtas, M. Salih .
INORGANICA CHIMICA ACTA, 2007, 360 (07) :2499-2502
[2]   Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine [J].
Arslan, Sonmez ;
Yilmaz, Ismail .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (04) :385-388
[3]  
BO SH, 2006, DYES PIGMENTS, V69, P1
[4]   Separation and mesogenic properties of tetraalkoxy-substituted phthalocyanine isomers [J].
Durmus, M ;
Yesilot, S ;
Ahsen, V .
NEW JOURNAL OF CHEMISTRY, 2006, 30 (05) :675-678
[5]   Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry [J].
Farren, C ;
Christensen, CA ;
FitzGerald, S ;
Bryce, MR ;
Beeby, A .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (26) :9130-9139
[6]   OPTICAL-ABSORPTION AND MAGNETIC CIRCULAR-DICHROISM STUDIES OF HYDROGEN, COPPER(II), ZINC(II), NICKEL(II), AND COBALT(II) CROWN ETHER-SUBSTITUTED MONOMERIC AND DIMERIC PHTHALOCYANINES [J].
GASYNA, Z ;
KOBAYASHI, N ;
STILLMAN, MJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (12) :2397-2405
[7]   Nanoscale organization of a phthalocyanine-fullerene system:: Remarkable stabilization of charges in photoactive 1-D nanotubules [J].
Guldi, DM ;
Gouloumis, A ;
Vázquez, P ;
Torres, T ;
Georgakilas, V ;
Prato, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5811-5813
[8]   Synthesis and solution properties of phthalocyanines substituted with four crown ethers [J].
Hamuryudan, E .
DYES AND PIGMENTS, 2006, 68 (2-3) :151-157
[9]   Synthesis of phthalocyanines with tridentate branched bulky and alkylthio groups [J].
Hamuryudan, E ;
Merey, S ;
Bayir, ZA .
DYES AND PIGMENTS, 2003, 59 (03) :263-268
[10]   Metal d-orbital occupation-dependent images in the scanning: Tunneling microscopy of metal phthalocyanines [J].
Hipps, KW ;
Lu, X ;
Wang, XD ;
Mazur, U .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (27) :11207-11210