Effect of NiO/YSZ compositions on the co-sintering process of anode-supported fuel cell

被引：62
作者：
Bao, WT [1 ]
Chang, QB [1 ]
Meng, GY [1 ]
机构：
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
来源：
JOURNAL OF MEMBRANE SCIENCE | 2005年 / 259卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
anode support; YSZ dense film; SOFC;
D O I：
10.1016/j.memsci.2005.03.009
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Effect of NiO/YSZ compositions on the co-sintering process of anode-supported fuel cell was researched. The green YSZ layer was fabricated by modifying electrostatic powder coating, and the relative density is about 52%. After co-firing at 1400 degrees C for 5h, the sample of YSZ film based on the 1000-NY support (pre-calcinated NiO 60wt.%, YSZ 40wt.%) is concave due to the mismatch of shrinkages between the YSZ film and anode support and there exist cracks on the film. Dense YSZ films based on the NY-20P (NiO 48wt.%, YSZ 32wt.% and graphite 20wt.%) support were fabricated after co-firing at 1400 degrees C for 2h. The OCV and the peak power density of a single cell with a 15 mu m thick YSZ film based on the NY-20P support are 1.09 V and 315 mW/cm(2) at 800 degrees C, respectively. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：103 / 109
页数：7
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