Dependence of the solubility of atmospheric oxygen in weakly alkaline aqueous solutions on surfactant concentration

被引:6
作者
Chistyakova, G. V. [1 ]
Koksharov, S. A. [1 ]
Vladimirova, T. V. [2 ]
机构
[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia
[2] Ivenergo, Ivanovo 153326, Russia
关键词
surfactants; molecular oxygen; solubility; critical micelle concentration;
D O I
10.1134/S0036024412110088
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubility of atmospheric oxygen in solutions of surfactants of different natures at 293 K and pH 8 is determined by gas chromatography. It is found that additives of nonionic surfactants decrease the oxygen content in the solution in the premicellar region and increase its solubility in the micellar region. It is shown that, for anionic surfactants, a decrease in the solubility of O-2 is observed over the entire concentration range.
引用
收藏
页码:1753 / 1755
页数:3
相关论文
共 10 条
  • [1] [Anonymous], 1998, METHODICAL GUIDELINE
  • [2] Absorption of Atmospheric Oxygen by Agitated Weakly Alkaline Solutions of Surfactants
    Chistyakova, G. V.
    Koksharov, S. A.
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2010, 83 (11) : 1930 - 1934
  • [3] Gorshkov A. I., 1986, ZH ANAL KHIM, V61, P146
  • [4] Groisman A.Sh., 1990, Russ. Chem. Rev., V59, P707, DOI [10.1070/RC1990v059n08ABEH003550, DOI 10.1070/RC1990V059N08ABEH003550]
  • [5] Khomutov N. E., 1974, ZH FIZ KHIM, V68, P621
  • [6] Lur'e Yu. Yu., 1984, ANAL CHEM IND WASTEW, P176
  • [7] Detection of bioactive surfactants in aqueous solutions on the basis of H2O2-voltammetry
    Navrátil, T
    Novotny, L
    [J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2000, 366 (03): : 249 - 253
  • [8] Schonfeld N., 1976, GRENZFLACHENAKTIVE A, P537
  • [9] Atmospheric and electrochemical oxidation of ascorbic acid in anionic, nonionic and cationic surfactant systems
    Szymula, M
    Narkiewicz-Michalek, J
    [J]. COLLOID AND POLYMER SCIENCE, 2003, 281 (12) : 1142 - 1148
  • [10] Yapar Saadet, 2000, Turkish Journal of Engineering and Environmental Sciences, V24, P365