Influence of Fe/Ba molar ratio on the characteristics of Ba-hexaferrite particles prepared by sol-gel combustion method

被引：76

作者：

Mali, A ^{[1
]}

Ataie, A ^{[1
]}

机构：

[1] Univ Tehran, Dept Met & Mat, Fac Engn, Tehran, Iran

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2005年 / 399卷 / 1-2期

关键词：

permanent magnets; sol-gel synthesis; X-ray diffraction; thermal analysis; magnetic measurements;

D O I：

10.1016/j.jallcom.2005.03.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nano-crystalline particles of barium hexaferrite (BaFe12I19) have been prepared by a sol-gel combustion technique using nitrate-citrate gels prepared from metal nitrates and citric acid solutions under various Fe/Ba molar ratios of 10, 11 and 12. The thermal decomposition process of the nitrate-citrate gels and as-burnt powders was investigated by XRD and DTA/TGA techniques. The results revealed that the nitrate citrate gels exhibit a self-propagating behavior after ignition and the single-phase barium hexaferrite formation temperature is significantly influenced by Fe/Ba molar ratio. The Fe/Ba molar ratio of 11 is more favorable for formation of barium hexaferrite. The SEM investigations revealed that the mean particle size of barium hexaferrite dramatically increases with increasing calcination temperature from 1000 to 1100 degrees C. The magnetic properties measured using a vibrating sample magnetometer (VSM) revealed that the sample synthesized under Fe/Ba molar ratio of 11, exhibits higher saturation magnetization in comparison with those synthesized under Fe/Ba molar ratios of 10 and 12. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：245 / 250

页数：6

共 25 条

[1] Microstructural aspects of the self-propagating high temperature synthesis of hexagonal barium ferrites in an external magnetic field [J].

Affleck, L ;

Aguas, MD ;

Parkin, IP ;

Pankhurst, QA ;

Kuznetsov, MV .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (08) :1925-1932

[2] Synthesis of barium hexaferrite by the co-precipitation method using acetate precursor [J].

Ataie, A ;

Heshmati-Manesh, S ;

Kazempour, H .

JOURNAL OF MATERIALS SCIENCE, 2002, 37 (10) :2125-2128

[3] Barium hexaferrite monodispersed nanoparticles prepared by the ceramic method [J].

Benito, G ;

Morales, MP ;

Requena, J ;

Raposo, V ;

Vázquez, M ;

Moya, JS .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2001, 234 (01) :65-72

[4] Structural and magnetic properties of barium hexaferrite nanostructured particles prepared by the combustion method [J].

Castro, S ;

Gayoso, M ;

Rivas, J ;

Greneche, JM ;

Mira, J ;

Rodriguez, C .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1996, 152 (1-2) :61-69

[5] BARIUM FERRITE PARTICULATES PREPARED BY A SALT-MELT METHOD [J].

CHIN, TS ;

HSU, SL ;

DENG, MC .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1993, 120 (1-3) :64-68

[6]

Kojima H., 1982, Ferromagnetic materials. A handbook on the properties of magnetically ordered substances. Vol.3, P305, DOI 10.1016/S1567-2719(82)03008-X

[7] The effect of the vacuum extraction and the Fe/Ba ratio on the phase formation of barium ferrite thin film synthesized by sol-gel method [J].