Probing noncovalent interactions in biomolecular crystals with terahertz spectroscopy

被引：33

作者：

Kleine-Ostmann, Thomas ^{[2
,4
]}

Wilk, Rafal ^{[2
]}

Rutz, Frank ^{[2
,5
]}

Koch, Martin ^{[2
]}

Niemann, Henning ^{[3
]}

Guettler, Bernd

Brandhorst, Kai ^{[1
]}

Grunenberg, Joerg ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Hochfrequenztech, D-38106 Braunschweig, Germany

[3] Phys Tech Bundesanstalt, D-38116 Braunschweig, Germany

[4] Phys Tech Bundesanstalt, Working Grp Electromagnet Fields, D-38116 Braunschweig, Germany

[5] Fraunhofer Inst Appl Solid State Phys, D-79108 Freiburg, Germany

来源：

CHEMPHYSCHEM | 2008年 / 9卷 / 04期

关键词：

computational chemistry; molecular crystals; noncovalent interactions; terahertz spectroscopy; vibrational spectroscopy;

D O I：

10.1002/cphc.200700729

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Graph Presented) Unique insights: The complexities of intermolecular interactions within biomolecular crystals (see figure, solid state thymine) are studied using a combination of spectroscopic and quantum-chemical techniques. Insights into the fundamental nature of the various low-frequency peaks is achieved and intra-vs intermolecular modes are distinguished. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：544 / 547

页数：4

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