Feedstocks, catalysts, process variables and techniques for biodiesel production by one-pot extraction-transesterification: a review

被引:25
作者
Ahmed, Mukhtar [1 ]
Abdullah, Anas [1 ]
Patle, Dipesh S. [2 ]
Shahadat, Mohammad [4 ]
Ahmad, Zainal [1 ]
Athar, Moina [3 ]
Aslam, Mohammad [1 ]
Vo, Dai-Viet N. [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Pulau Pinang, Malaysia
[2] Motilal Nehru Natl Inst Technol Allahabad, Chem Engn Dept, Prayagraj 211004, UP, India
[3] Aligarh Muslim Univ, Zakir Hussain Coll Engn & Technol, Dept Petr Studies, Aligarh, Uttar Pradesh, India
[4] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
关键词
Biodiesel; One-pot extraction-transesterification; Intensification techniques; Feedstocks; Catalysts; IN-SITU TRANSESTERIFICATION; JATROPHA-CURCAS L; SPENT COFFEE GROUNDS; WET MICROALGAL BIOMASS; ACID METHYL-ESTERS; MICROWAVE-ASSISTED TRANSESTERIFICATION; TRIADICA-SEBIFERA L; REACTIVE-EXTRACTION; EMISSION CHARACTERISTICS; CHLORELLA-VULGARIS;
D O I
10.1007/s10311-021-01358-w
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biodiesel is a sustainable alternative to petroleum diesel. The main bottlenecks in the commercialization of biodiesel are production costs and suitable industrial techniques to process feedstocks. This can be solved by one-pot extraction-transesterification of cheap, low-quality feedstocks. Here we review one-pot extraction-transesterification using agricultural seed crops, oleaginous microbial biomass and biological refuse, with focus on catalysis. Catalysts such as acetyl chloride, sodium hydroxide, sulphonated rice husk and calcium oxide have shown to be efficient with conversion in the range of 95-100%. We present intensification techniques such as microwave irradiation, ultrasonication, coupled microwave and ultrasound, thermally assisted and solvothermal processes.
引用
收藏
页码:335 / 378
页数:44
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