Colloidal and Nanosized Catalysts in Organic Synthesis: XXIII. Reductive Amination of Carbonyl Compounds Catalyzed by Nickel Nanoparticles in a Plug-Flow Reactor

被引：4
作者：
Mokhov, V. M. [1 ]
Popov, Yu. V. [1 ]
Paputina, A. N. [1 ]
Nebykov, D. N. [1 ]
Shishkin, E. V. [1 ]
机构：
[1] Volgograd State Tech Univ, Volgograd 400005, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2019年 / 89卷 / 12期
关键词：
catalysis; nanoparticles; nickel; hydrogenation; reductive amination; amines; CONTINUOUS HYDROGENATION; TERTIARY-AMINES; KETONES; ALDEHYDES; ALKYLATION; SUPPORT;
D O I：
10.1134/S1070363219120016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reductive amination of aldehydes and ketones with primary and secondary amines under catalysis with nickel nanoparticles supported on zeolite X, MgO, or activated carbon in the gas phase or in the gas-liquid system in a plug-flow reactor proceeds at atmospheric pressure of hydrogen with the formation of secondary or tertiary amines in high yield.
引用
收藏
页码：2333 / 2340
页数：8
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