Self-assembling sulfonated graphene/polyaniline nanocomposite paper for high performance supercapacitor

被引:45
作者
Fan, Tianju [1 ]
Tong, Songzhao [1 ]
Zeng, Wenjin [1 ]
Niu, Qiaoli [1 ]
Liu, Yidong [2 ,3 ]
Kao, Chi-Yu [4 ]
Liu, Jieyu [5 ]
Huang, Wei [1 ,2 ,3 ]
Min, Yong [1 ,4 ]
Epstein, Arthur J. [4 ]
机构
[1] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China
[2] State Key Lab Organ Elect & Informat Displays, Yancheng 224000, Jiangsu, Peoples R China
[3] Fountain Global Photoelect Technol Co Ltd, Yancheng 224000, Jiangsu, Peoples R China
[4] Ohio State Univ, Dept Phys & Chem & Biochem, Columbus, OH 43210 USA
[5] Chengdu Text Coll, Text Printing Chem & Environm Engn Dept, Chengdu 611731, Sichuan, Peoples R China
关键词
Sulfonated graphene (SG); Polyaniline (PANI); Graphene/PANI; Sulfonated graphene/PANI (SG/PANI); Supercapacitors; GRAPHENE; POLYANILINE; FILMS; OXIDE; COMPOSITES; ELECTRODES; SHEETS; CARBON;
D O I
10.1016/j.synthmet.2014.11.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We reported a low cost and high efficient method to fabricate free-standing sulfonated graphene/polyaniline (SG/PANI) nanocomposite papers. The nanocomposite paper had layered structure, and polyaniline (PANI) was uniformly intercalated into the sulfonated graphene layers. The nanostructured PANI was coated on the surface of individual SG sheets. It was found that the sulfonated graphene actually acted as dopants to dope with the PANI. The SG/PANI nanocomposite papers had thin, lightweight, and flexible characters and its supercapacitor devices displayed excellent electrochemical performance in terms of ratio capacitance and good cycling stability. Its ratio capacitance reached 478 F/g at a discharge rate of 0.5 A/g and its capacitance retention rate maintained 88% of its original capacitance after 2000 cycles. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 86
页数:8
相关论文
共 38 条
[1]   Ultracapacitors: why, how, and where is the technology [J].
Burke, A .
JOURNAL OF POWER SOURCES, 2000, 91 (01) :37-50
[2]   The Role of Nanostructure in Improving the Performance of Electrodes for Energy Storage and Conversion [J].
Centi, Gabriele ;
Perathoner, Siglinda .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (26) :3851-3878
[3]   Flexible graphene-polyaniline composite paper for high-performance supercapacitor [J].
Cong, Huai-Ping ;
Ren, Xiao-Chen ;
Wang, Ping ;
Yu, Shu-Hong .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1185-1191
[4]   Synthesis of sulfonated graphene/polyaniline composites with improved electroactivity [J].
Coskun, Elcin ;
Zaragoza-Contreras, Erasto A. ;
Salavagione, Horacio J. .
CARBON, 2012, 50 (06) :2235-2243
[5]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[6]   Morphology-controlled fabrication of sulfonated graphene/polyaniline nanocomposites by liquid/liquid interfacial polymerization and investigation of their electrochemical properties [J].
Hao, Qingli ;
Wang, Hualan ;
Yang, Xujie ;
Lu, Lude ;
Wang, Xin .
NANO RESEARCH, 2011, 4 (04) :323-333
[7]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[8]   Layer-by-layer assembled electrochromic films for all-solid-state electrochromic devices [J].
Kim, E ;
Jung, S .
CHEMISTRY OF MATERIALS, 2005, 17 (25) :6381-6387
[9]   Hybrid multilayer thin film supercapacitor of graphene nanosheets with polyaniline: importance of establishing intimate electronic contact through nanoscale blending [J].
Lee, Taemin ;
Yun, Taeyeong ;
Park, Byeongho ;
Sharma, Bhawana ;
Song, Hyun-Kon ;
Kim, Byeong-Su .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (39) :21092-21099
[10]   Free-standing 3D polyaniline-CNT/Ni-fiber hybrid electrodes for high-performance supercapacitors [J].
Li, Yuan ;
Fang, Yuzhu ;
Liu, Hong ;
Wu, Xiaoming ;
Lu, Yong .
NANOSCALE, 2012, 4 (09) :2867-2869