Recent advances in copper-catalyzed oxidation of organic compounds

被引：301

作者：

Punniyamurthy, T. ^{[1
]}

Rout, Laxmidhar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 1-2期

关键词：

oxidation; organic compounds; copper catalysts; molecular oxygen; hydroperoxide; peroxyester; iodosylbenzene;

D O I：

10.1016/j.ccr.2007.04.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The copper-catalyzed oxidation of organic compounds has made considerable progress in the recent years. Molecular oxygen, aqueous hydrogen peroxide, tert-butyl hydroperoxide and peroxyesters have been employed as terminal oxidants for this purpose. The use of polymer and solid-supported catalysts, ionic liquids and fluorous biphase systems (FBS) has been demonstrated to facilitate the recyclability of the catalysts. Efforts have been made for the aqueous oxidation processes employing water-soluble copper complexes. Chiral catalysts have been designed and developed for the enantioselective oxidative coupling of 2-naphthols, Baeyer-Villiger oxidation and Kharasch-Sosnovsky reaction with high enantioselectivity. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：134 / 154

页数：21

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