Fluorinated alcohols: Effective solvents for uncatalysed epoxidations with aqueous hydrogen peroxide

被引：1
|
作者：
van Vliet, MCA [1 ]
Arends, IWCE [1 ]
Sheldon, RA [1 ]
机构：
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands
来源：
SYNLETT | 2001年 / 02期
关键词：
epoxidation; alkenes; electrophilic addition; hydrogen peroxide; fluoro alcohols;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Buffered aqueous hydrogen peroxide in combination with fluorinated alcohols (trifluoroethanol at reflux temperature or hexafluoro-2-propanol at room temperature) oxidises a variety of alkenes to the corresponding epoxides in high rates and fairly high yields, without the need for any catalyst.
引用
收藏
页码：248 / 250
页数：3
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