Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination

被引：0
作者：
Sturm, Jaka [1 ]
Modec, Barbara [1 ]
机构：
[1] Univ Ljubljana, Dept Chem & Chem Technol, Vecna Pot 113, Ljubljana 1000, Slovenia
来源：
MOLBANK | 2021年 / 2021卷 / 03期
关键词：
pentachloridooxomolybdate(V); molybdenum; coordination chemistry; crystal structure; ELECTRONIC-STRUCTURES; OXOMOLYBDENUM(V); COMPLEXES; MOLYBDENUM(V); COFACTORS; ENZYMES;
D O I：
10.3390/M1249
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
(PyH)(2)[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)(5)[MoOCl4(H2O)](3)Cl-2 in acetonitrile. (PyH)(2)[MoOCl5] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl5](2-) ion displays the usual structural characteristics of the mononuclear MoO3+-containing compounds.
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页数：6
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