Transition-metal complexes of an open geodesic polyarene

被引：77

作者：

Petrukhina, MA ^{[1
]}

Andreini, KW

Mack, J

Scott, LT

机构：

[1] SUNY Albany, Dept Chem, Albany, NY 12222 USA

[2] Boston Coll, Dept Chem, Merkert Chem Ctr, Boston, MA 02167 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 29期

关键词：

aromaticity; carboxylates; corannulene; pi interactions; rhodium; structure elucidation;

D O I：

10.1002/anie.200351403

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Corannulene, the smallest subunit of C60 that retains a curved surface, forms crystalline η2-coordinated π complexes with dirhodium(II) tetrakis(trifluoroacetate) by using solvent-free gas-phase deposition. As many as three metal atoms coordinate to the double bonds found at the rim of each corannulene, with one such atom always located on the concave surface (see picture).

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页码：3375 / 3379

页数：5

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