Preconcentration, separation and spectrophotometric determination of aluminium(III) in water samples and dialysis concentrates at trace levels with 8-hydroxyquinoline-cobalt(II) coprecipitation system

被引:55
作者
Bulut, Volkan Numan [2 ]
Arslan, Deniz [3 ]
Ozdes, Duygu [3 ]
Soylak, Mustafa [1 ]
Tufekci, Mehmet [3 ]
机构
[1] Erciyes Univ, Fac Sci, Dept Chem, TR-38039 Kayseri, Turkey
[2] Karadeniz Tech Univ, Macka Vocat Sch, TR-61750 Trabzon, Turkey
[3] Karadeniz Tech Univ, Dept Chem, Fac Arts & Sci, TR-61080 Trabzon, Turkey
关键词
Determination of aluminium; Coprecipitation; 8-Hydroxyquinoline; Preconcentration; UV-vis spectrometry; Dialysis concentrates; ATOMIC-ABSORPTION-SPECTROMETRY; SOLID-PHASE EXTRACTION; CLOUD POINT EXTRACTION; HYDROXIDE COPRECIPITATION; EMISSION-SPECTROMETRY; NATURAL-WATERS; WASTE-WATER; METAL IONS; LEAD; CHROMIUM;
D O I
10.1016/j.jhazmat.2010.06.034
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A separation-preconcentration procedure was developed for the determination of trace amounts of aluminium in water samples and dialysis concentrates by UV-vis Spectrophotometry after coprecipitation using 8-hydroxyquinoline (8-HQ) as a chelating agent and Co(II) as a carrier element. This procedure is based on filtration of the solution containing precipitate on a cellulose nitrate membrane filter following aluminium(III) coprecipitation with Co/8-HQ and then the precipitates together with membrane filter were dissolved in concentrated nitric acid. The metal contents of the final solution were determined by UV-vis Spectrophotometry with Erio Chrome Cyanine-R standard method. Several parameters including pH of sample solution, amount of carrier element and reagent, standing time, sample volume for precipitation and the effects of diverse ions were examined. The enrichment factor was calculated as 50 and the detection limits, corresponding to three times the standard deviation of the blank (N: 10), was found to be 0.2 mu g L(-1). The accuracy of the method was tested with standard reference material (CRM-TMDW-500) and spiked addition. Determination of aluminium(III) was carried out in sea water, river water, tap water and haemodialysis fluids samples. The recoveries were >95%. The relative standard deviations of determination were less than 6%. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:331 / 336
页数:6
相关论文
共 48 条
  • [1] Kinetic-spectrophotometry method for determination of ultra trace amounts of aluminum in food samples
    Abbasi, Shahryar
    Farmany, Abbas
    Gholivand, Mohammad Bagher
    Naghipour, Ali
    Abbasi, Freshteh
    Khani, Hossein
    [J]. FOOD CHEMISTRY, 2009, 116 (04) : 1019 - 1023
  • [2] Co-precipitative pre-concentration with sodium diethyldithiocarbamate and ICP-AES determination of Se, Cu, Pb, Zn, Fe, Co, Ni, Mn, Cr and Cd in water
    Atanassova, D
    Stefanova, V
    Russeva, E
    [J]. TALANTA, 1998, 47 (05) : 1237 - 1243
  • [3] PRECONCENTRATION BY COPRECIPITATION OF LEAD AND SELENIUM WITH NI PYRROLIDINE DITHIOCARBAMATE COMPLEX AND THEIR SIMULTANEOUS DETERMINATION BY INTERNAL STANDARD ATOMIC-ABSORPTION SPECTROMETRY WITH THE SOLID SAMPLING TECHNIQUE
    ATSUYA, I
    ITOH, K
    ARIU, K
    [J]. PURE AND APPLIED CHEMISTRY, 1991, 63 (09) : 1221 - 1226
  • [4] Quantification of trace elements by sector field inductively coupled plasma mass spectrometry in urine, serum, blood and cerebrospinal fluid of patients with Parkinson's disease
    Bocca, B
    Alimonti, A
    Petrucci, F
    Violante, N
    Sancesario, G
    Forte, G
    Senofonte, O
    [J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2004, 59 (04) : 559 - 566
  • [5] Carrier element-free coprecipitation (CEFC) method for the separation, preconcentration and speciation of chromium using an isatin derivative
    Bulut, Volkan Numan
    Ozdes, Duygu
    Bekircan, Olcay
    Gundogdu, Ali
    Duran, Celal
    Soylak, Mustafa
    [J]. ANALYTICA CHIMICA ACTA, 2009, 632 (01) : 35 - 41
  • [6] Aluminum determination in biological fluids and dialysis concentrates via chelation with 8-hydroxyquinoline and solvent extraction/fluorimetry
    Buratti, M.
    Valla, C.
    Pellegrino, O.
    Rubino, F. M.
    Colombi, A.
    [J]. ANALYTICAL BIOCHEMISTRY, 2006, 353 (01) : 63 - 68
  • [7] Chronic exposure to aluminum in drinking water increases inflammatory parameters selectively in the brain
    Campbell, A
    Becaria, A
    Lahiri, DK
    Sharman, K
    Bondy, SC
    [J]. JOURNAL OF NEUROSCIENCE RESEARCH, 2004, 75 (04) : 565 - 572
  • [8] Determination of trace amounts of some metals in samples with high salt content by atomic absorption spectrometry after cobalt-diethyldithiocarbamate coprecipitation
    Elci, L
    Sahin, U
    Oztas, S
    [J]. TALANTA, 1997, 44 (06) : 1017 - 1023
  • [9] Coprecipitation of Cu(II), Ni(II), Fe(III), Cd(II), Pb(II), and Co(II) in wastewater, sediment, and metallic zinc samples with HMDTC-HMA for flame atomic absorption spectrometric determination
    Elçi, L
    Soylak, M
    Özcan, B
    [J]. ANALYTICAL LETTERS, 2003, 36 (05) : 987 - 999
  • [10] Speciation of aluminum in tea infusion by ion-exchange resins and flame AAS detection
    Erdemoglu, SB
    Pyrzyniska, K
    Güçer, S
    [J]. ANALYTICA CHIMICA ACTA, 2000, 411 (1-2) : 81 - 89