Determination of Kerr and two-photon absorption coefficients of indandione derivatives

被引:0
|
作者
Bundulis, Arturs [1 ]
Mihailovs, Igors [1 ]
Nitiss, Edgars [1 ]
Busenbergs, Janis [1 ]
Rutkis, Martins [1 ]
机构
[1] Univ Latvia, Inst Solid State Phys, Kengaraga 8, LV-1068 Riga, Latvia
来源
关键词
Kerr effect; two-photon absorption; organic materials; nonlinear optics; Z-scan; Z-SCAN; OPTICAL NONLINEARITIES; SUSCEPTIBILITY; DEPENDENCE;
D O I
10.1117/12.2265389
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We studied nonlinear optical properties of two different aminobenziliden-1,3-indandione derivatives -DDMABI and DMABI-OH by employing the Z-scan method. Through this we described how different donor and acceptor groups influence third-order nonlinear optical properties such as Kerr effect and two-photon absorption. During experimental measurements we used 1064 nm Nd: YAG laser with 30 ps pulse duration and 10 Hz repetition rate. From acquired values of Kerr and two-photon absorption coefficients we calculated values for real and imaginary parts of third-order susceptibility, as well as second-order hyperpolarizability. Quantum chemical calculations were carried out for second-order hyperpolarizability to study how well calculations correlate with experimental values. Acquired data for DDMABI and DMABI-OH were compared with data for other ABI derivatives studied previously.
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页数:8
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