Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

被引：8
|
作者：
Bai, Shi-Qiang [1 ]
Ke, Karen Lin [1 ]
Young, David James [1 ,2 ]
Hor, T. S. Andy [1 ,3 ]
机构：
[1] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore
[2] Univ Sunshine Coast, Fac Sci Hlth Educ & Engn, Maroochydore, Qld 4558, Australia
[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 849-850卷
关键词：
Bis(triazole) ligand; Cubane-like [Cu4I4] cluster; Coordination polymer; Luminescence; COPPER(I) IODIDE; LUMINESCENCE PROPERTIES; TERMINAL ALKYNES; COMPLEXES; THERMOCHROMISM; CONSTRUCTION; EMISSION; AZIDES; NET;
D O I：
10.1016/j.jorganchem.2017.03.040
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[L2Cu4I4](n) (1) based on a cubic [Cu4I4] node and ditopic, bridging bis(triazole) (L = 2,6-bis((1H-1,2,3-triazol-1-yl)methyl)pyridine) is a unique and highly symmetric cubane cluster based coordination polymer with strong yellow emission. Comparison with similar coordination polymers permits a structure activity relationship and reveals that the emission energy for these [Cu4I4] cluster-based materials occurs in the mid-range of Cu center dot center dot center dot Cu distances and tetrahedral geometry index values. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：137 / 141
页数：5
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